Physical Principles and Techniques of Protein Chemistry, Part 3 |
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Page 12
The corresponding relation for $ ' is * - = [ - ( - ) . ] ( 19 ) Since the masses of the
diffusible components are not held constant under isopotential conditions but
may vary unpredictably as the concentration of a nondiffusible component is
varied ...
The corresponding relation for $ ' is * - = [ - ( - ) . ] ( 19 ) Since the masses of the
diffusible components are not held constant under isopotential conditions but
may vary unpredictably as the concentration of a nondiffusible component is
varied ...
Page 456
3a — that is , the CD band corresponding to a negative Cotton effectwould
appear as the mirror image ( through the horizontal axis ) of the CD curve in Fig .
3b ; likewise , the ORD curve associated with a positive Cotton effect would
resemble ...
3a — that is , the CD band corresponding to a negative Cotton effectwould
appear as the mirror image ( through the horizontal axis ) of the CD curve in Fig .
3b ; likewise , the ORD curve associated with a positive Cotton effect would
resemble ...
Page 481
16 Therefore , if Eq . ( 41 ) corresponds to a local transition which is magnetically
allowed ( mimo = mjao = mkao # 0 ) but ... Tinoco specifically recommended
using this expression ( corresponding to his Eq . III - 24 ) for calculating the
rotational ...
16 Therefore , if Eq . ( 41 ) corresponds to a local transition which is magnetically
allowed ( mimo = mjao = mkao # 0 ) but ... Tinoco specifically recommended
using this expression ( corresponding to his Eq . III - 24 ) for calculating the
rotational ...
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absorption acid addition angle appears application approximately B-structure band becomes calculated CD spectra Chem compared complex component concentration conformation constant containing contribution corresponding Cotton effects density dependence derived described determined diffusible discussed electron enzyme equation equilibrium estimate et al example experimental experiments expression factor field function given gives helical helix increased indicated intensity interaction length magnetic measurements mechanism method molecular weight molecule negative observed obtained optical activity osmotic parameters partial positive possible pressure procedure protein protein solution quantum mechanical radius range reference region relative residues respectively rotational strength sample scattering curve shape shown shows side similar solution solvent specific volume spectrum structure studies Table temperature theoretical theory tion transition transition dipole moment usually various vary volume wavelength X-ray zero