Physical Principles and Techniques of Protein Chemistry, Part 3Sydney J. Leach |
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Page 262
... effect . For example , the effect of Mn2 + ions on the T1 value of 3 sec for pure water is illustrated in Fig . 10 . 1 The local fields fluctuate both in magnitude and direction in a random manner due to the various atomic or molecular ...
... effect . For example , the effect of Mn2 + ions on the T1 value of 3 sec for pure water is illustrated in Fig . 10 . 1 The local fields fluctuate both in magnitude and direction in a random manner due to the various atomic or molecular ...
Page 396
... effect solution adequately represents the experimental ORD although a three Cotton effect solution improves the fit to within experimental error . In the two Cotton effect solution a negative band is centered at 198 nm and a positive ...
... effect solution adequately represents the experimental ORD although a three Cotton effect solution improves the fit to within experimental error . In the two Cotton effect solution a negative band is centered at 198 nm and a positive ...
Page 416
... effect at about 220 nm . However , in the helical form at pH 5.78 , this becomes a negative Cotton effect . Thus the n- * Cotton effect of the a - helix may overshadow the side - chain Cotton effects ( see , e.g. , Beychok , 1967 ) ...
... effect at about 220 nm . However , in the helical form at pH 5.78 , this becomes a negative Cotton effect . Thus the n- * Cotton effect of the a - helix may overshadow the side - chain Cotton effects ( see , e.g. , Beychok , 1967 ) ...
Contents
25 | 4 |
E The Isopotential Specific Volume | 10 |
Direct Volume Change | 22 |
Copyright | |
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a-helical a-helix absorption band acid angle B-structure Beychok Biochem Biochemistry Biol Blout c₂ calculated CD band CD spectrum Chem chromophore circular dichroism coefficient Cohn coil complex concentration conformation contribution Cotton effects creatine kinase cross-section denatured determined dipole Doty electron density ellipticity enzyme equation equilibrium exciton experimental factor Fasman function helical content helix intensity interaction kinase Kratky lysozyme magnetic measurements method Moffitt molecular weight molecule myoglobin negative negative band obtained optical activity ORD curve parameters partial specific volume particles peptide perturbation Phys Pilz plot polarized poly-L-proline polymer polypeptides positive procedure protein protein solution pulse Pysh radius of gyration random coil region residues rotational strength rotatory sample Schellman Section shape small-angle solvent spectra sphere studies subunits T₁ temperature theory Tinoco tion transition transition dipole moment tyrosine vector wavefunctions wavelength Woody X-ray zero