## Physical Principles and Techniques of Protein Chemistry, Part 3 |

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Page 372

Even before the derivation of the Rosenfeld

Drude - type

In the general case a multiterm Drude

...

Even before the derivation of the Rosenfeld

**equation**, it had been known thatDrude - type

**equations**could describe the rotation outside of absorption bands .In the general case a multiterm Drude

**equation**of the form [ m ' la = Said : 2 / ( 22...

Page 382

Since the Moffitt

should apply for any optically active molecule in regions distant from absorption

bands , we can carry out a similar expansion of this

Since the Moffitt

**equation**is derivable from the multiterm Drude**equation**, whichshould apply for any optically active molecule in regions distant from absorption

bands , we can carry out a similar expansion of this

**equation**for the random coil ...Page 389

In the Moffitt

combining the use of a ' , and b ' . values . ...

two

and the ...

In the Moffitt

**equation**one is able to cancel these effects to some extent bycombining the use of a ' , and b ' . values . ...

**Equation**So far we have suggestedtwo

**equations**for analyzing the ORD curves of proteins — the Moffitt**equation**and the ...

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absorption acid addition angle appears application approximately B-structure band becomes calculated CD spectra Chem compared complex component concentration conformation constant containing contribution corresponding Cotton effects density dependence derived described determined diffusible discussed electron enzyme equation equilibrium estimate et al example experimental experiments expression factor field function given gives helical helix increased indicated intensity interaction length magnetic measurements mechanism method molecular weight molecule negative observed obtained optical activity osmotic parameters partial positive possible pressure procedure protein protein solution quantum mechanical radius range reference region relative residues respectively rotational strength sample scattering curve shape shown shows side similar solution solvent specific volume spectrum structure studies Table temperature theoretical theory tion transition transition dipole moment usually various vary volume wavelength X-ray zero