Physical Principles and Techniques of Protein Chemistry, Part 3Sydney J. Leach |
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Page 372
... equation , it had been known that Drude - type equations could describe the rotation outside of absorption bands . In the general case a multiterm Drude equation of the form [ m ' ] = Σ a‚d‚3 / ( x2 — λ ; 2 ) ( 16 ) may be used . Here a ...
... equation , it had been known that Drude - type equations could describe the rotation outside of absorption bands . In the general case a multiterm Drude equation of the form [ m ' ] = Σ a‚d‚3 / ( x2 — λ ; 2 ) ( 16 ) may be used . Here a ...
Page 382
... equation is derivable from the multiterm Drude equation , which should apply for any optically active molecule in regions distant from absorption bands , we can carry out a similar expansion of this equation for the random coil ...
... equation is derivable from the multiterm Drude equation , which should apply for any optically active molecule in regions distant from absorption bands , we can carry out a similar expansion of this equation for the random coil ...
Page 389
... equation one is able to cancel these effects to some extent by combining the use of a ' , and b'o values . 2. The Moffitt Equation and the Two - Term Drude Equation So far we have suggested two equations for analyzing the ORD curves of ...
... equation one is able to cancel these effects to some extent by combining the use of a ' , and b'o values . 2. The Moffitt Equation and the Two - Term Drude Equation So far we have suggested two equations for analyzing the ORD curves of ...
Contents
25 | 4 |
E The Isopotential Specific Volume | 10 |
Direct Volume Change | 22 |
Copyright | |
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a-helical a-helix absorption band acid angle B-structure Beychok Biochem Biochemistry Biol Blout c₂ calculated CD band CD spectrum Chem chromophore circular dichroism coefficient Cohn coil complex concentration conformation contribution Cotton effects creatine kinase cross-section denatured determined dipole Doty electron density ellipticity enzyme equation equilibrium exciton experimental factor Fasman function helical content helix intensity interaction kinase Kratky lysozyme magnetic measurements method Moffitt molecular weight molecule myoglobin negative negative band obtained optical activity ORD curve parameters partial specific volume particles peptide perturbation Phys Pilz plot polarized poly-L-proline polymer polypeptides positive procedure protein protein solution pulse Pysh radius of gyration random coil region residues rotational strength rotatory sample Schellman Section shape small-angle solvent spectra sphere studies subunits T₁ temperature theory Tinoco tion transition transition dipole moment tyrosine vector wavefunctions wavelength Woody X-ray zero