Physical Principles and Techniques of Protein Chemistry, Part 3Sydney J. Leach |
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Page 95
... ionic strength of the aqueous solvent medium . ( The student can easily prove to himself that the ionic im- balance decreases with salt concentration by simulating a system at fixed net charge and number of moles of protein and then ...
... ionic strength of the aqueous solvent medium . ( The student can easily prove to himself that the ionic im- balance decreases with salt concentration by simulating a system at fixed net charge and number of moles of protein and then ...
Page 96
... ionic species fixes the concentration ratio for any other ion in the particular system . We note also that a Donnan effect dictates that the two sides at equilibrium be at a different pH , a commonly ob- served phenomenon with proteins ...
... ionic species fixes the concentration ratio for any other ion in the particular system . We note also that a Donnan effect dictates that the two sides at equilibrium be at a different pH , a commonly ob- served phenomenon with proteins ...
Page 118
... ionic strength is equal to the molality of an uni - univalent salt . Transposing and solving for v gives V = √4m3 ( BM2 – ẞ22 / 2 ) ( 39 ) A large value for the Donnan term has been found to contribute the major positive deviation from ...
... ionic strength is equal to the molality of an uni - univalent salt . Transposing and solving for v gives V = √4m3 ( BM2 – ẞ22 / 2 ) ( 39 ) A large value for the Donnan term has been found to contribute the major positive deviation from ...
Contents
25 | 4 |
E The Isopotential Specific Volume | 10 |
Direct Volume Change | 22 |
Copyright | |
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a-helical a-helix absorption band acid angle B-structure Beychok Biochem Biochemistry Biol Blout c₂ calculated CD band CD spectrum Chem chromophore circular dichroism coefficient Cohn coil complex concentration conformation contribution Cotton effects creatine kinase cross-section denatured determined dipole Doty electron density ellipticity enzyme equation equilibrium exciton experimental factor Fasman function helical content helix intensity interaction kinase Kratky lysozyme magnetic measurements method Moffitt molecular weight molecule myoglobin negative negative band obtained optical activity ORD curve parameters partial specific volume particles peptide perturbation Phys Pilz plot polarized poly-L-proline polymer polypeptides positive procedure protein protein solution pulse Pysh radius of gyration random coil region residues rotational strength rotatory sample Schellman Section shape small-angle solvent spectra sphere studies subunits T₁ temperature theory Tinoco tion transition transition dipole moment tyrosine vector wavefunctions wavelength Woody X-ray zero