Physical Principles and Techniques of Protein Chemistry, Part 3Sydney J. Leach |
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Page 368
... peptide chromophore . For static charges the in- duced optical activity is proportional to r3 or r1 ( Schellman and Oriel , 1962 ; Caldwell and Eyring , 1963 ) so that this mechanism is most im- portant only for short - range ...
... peptide chromophore . For static charges the in- duced optical activity is proportional to r3 or r1 ( Schellman and Oriel , 1962 ; Caldwell and Eyring , 1963 ) so that this mechanism is most im- portant only for short - range ...
Page 372
... peptide chromophore vary with the confor- mation of the backbone chain since , as we have already pointed out , the peptide bond itself is symmetric ( Section II ) . If the following assumptions are made : 1. the protein structure can ...
... peptide chromophore vary with the confor- mation of the backbone chain since , as we have already pointed out , the peptide bond itself is symmetric ( Section II ) . If the following assumptions are made : 1. the protein structure can ...
Page 394
... Peptide Cotton Effects Although the rotatory dispersion of proteins in the visible can be represented by Eq . ( 16 ) and its derivatives we have already seen ( Fig . 1 ) that in the vicinity ... Peptide Cotton Effects Peptide Cotton Effects.
... Peptide Cotton Effects Although the rotatory dispersion of proteins in the visible can be represented by Eq . ( 16 ) and its derivatives we have already seen ( Fig . 1 ) that in the vicinity ... Peptide Cotton Effects Peptide Cotton Effects.
Contents
25 | 4 |
E The Isopotential Specific Volume | 10 |
Direct Volume Change | 22 |
Copyright | |
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a-helical a-helix absorption band acid angle B-structure Beychok Biochem Biochemistry Biol Blout c₂ calculated CD band CD spectrum Chem chromophore circular dichroism coefficient Cohn coil complex concentration conformation contribution Cotton effects creatine kinase cross-section denatured determined dipole Doty electron density ellipticity enzyme equation equilibrium exciton experimental factor Fasman function helical content helix intensity interaction kinase Kratky lysozyme magnetic measurements method Moffitt molecular weight molecule myoglobin negative negative band obtained optical activity ORD curve parameters partial specific volume particles peptide perturbation Phys Pilz plot polarized poly-L-proline polymer polypeptides positive procedure protein protein solution pulse Pysh radius of gyration random coil region residues rotational strength rotatory sample Schellman Section shape small-angle solvent spectra sphere studies subunits T₁ temperature theory Tinoco tion transition transition dipole moment tyrosine vector wavefunctions wavelength Woody X-ray zero