Physical Principles and Techniques of Protein Chemistry, Part 3Sydney J. Leach |
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Page 246
... relaxation time spin - spin proton relaxation time enhancement factor contribution of paramagnetic species to observed T1 of water molecules mole fraction of water molecules in the first coordination sphere of a para- magnetic species ...
... relaxation time spin - spin proton relaxation time enhancement factor contribution of paramagnetic species to observed T1 of water molecules mole fraction of water molecules in the first coordination sphere of a para- magnetic species ...
Page 263
... relaxation time T1 , p with manganese concentra- tion , at 22 ° C . The fluctuating nature of the local field is described quantitatively in the theory of random processes by a correlation time Te . This may be interpreted qualitatively ...
... relaxation time T1 , p with manganese concentra- tion , at 22 ° C . The fluctuating nature of the local field is described quantitatively in the theory of random processes by a correlation time Te . This may be interpreted qualitatively ...
Page 265
... relaxation decreases rapidly with distance according to an inverse sixth - power law , the direct or outer - sphere relaxation is negligible and may safely be ignored . By the same token , there is a strong interaction between the ...
... relaxation decreases rapidly with distance according to an inverse sixth - power law , the direct or outer - sphere relaxation is negligible and may safely be ignored . By the same token , there is a strong interaction between the ...
Contents
25 | 4 |
E The Isopotential Specific Volume | 10 |
Direct Volume Change | 22 |
Copyright | |
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a-helical a-helix absorption band acid angle B-structure Beychok Biochem Biochemistry Biol Blout c₂ calculated CD band CD spectrum Chem chromophore circular dichroism coefficient Cohn coil complex concentration conformation contribution Cotton effects creatine kinase cross-section denatured determined dipole Doty electron density ellipticity enzyme equation equilibrium exciton experimental factor Fasman function helical content helix intensity interaction kinase Kratky lysozyme magnetic measurements method Moffitt molecular weight molecule myoglobin negative negative band obtained optical activity ORD curve parameters partial specific volume particles peptide perturbation Phys Pilz plot polarized poly-L-proline polymer polypeptides positive procedure protein protein solution pulse Pysh radius of gyration random coil region residues rotational strength rotatory sample Schellman Section shape small-angle solvent spectra sphere studies subunits T₁ temperature theory Tinoco tion transition transition dipole moment tyrosine vector wavefunctions wavelength Woody X-ray zero