Physical Principles and Techniques of Protein Chemistry, Part 3Sydney J. Leach |
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Page 484
... transition dipole moments for the system . = The electric transition dipole moments of the system are found from the following equation u ' = u uC ( 52 ) where the elements of μ ( a row vector ) are the transition moments of the ...
... transition dipole moments for the system . = The electric transition dipole moments of the system are found from the following equation u ' = u uC ( 52 ) where the elements of μ ( a row vector ) are the transition moments of the ...
Page 490
... transitions optically active . ( Note that an inherently optically active transition may acquire additional optical activity in this way . ) Such a perturbing environment could be produced by the remainder of the mole- cule containing ...
... transitions optically active . ( Note that an inherently optically active transition may acquire additional optical activity in this way . ) Such a perturbing environment could be produced by the remainder of the mole- cule containing ...
Page 501
... transition a of group 1 ) and the sition of the other amide ( transition b of group 2 ) . From Eq . ( 48a ) , appropriate expression for the rotational strength R1a of the n1- tran- sition here is21 Ria = + V12Im [ μ2 m1 ] 2λoλa2 hc ...
... transition a of group 1 ) and the sition of the other amide ( transition b of group 2 ) . From Eq . ( 48a ) , appropriate expression for the rotational strength R1a of the n1- tran- sition here is21 Ria = + V12Im [ μ2 m1 ] 2λoλa2 hc ...
Contents
25 | 4 |
E The Isopotential Specific Volume | 10 |
Direct Volume Change | 22 |
Copyright | |
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a-helical a-helix absorption band acid angle B-structure Beychok Biochem Biochemistry Biol Blout c₂ calculated CD band CD spectrum Chem chromophore circular dichroism coefficient Cohn coil complex concentration conformation contribution Cotton effects creatine kinase cross-section denatured determined dipole Doty electron density ellipticity enzyme equation equilibrium exciton experimental factor Fasman function helical content helix intensity interaction kinase Kratky lysozyme magnetic measurements method Moffitt molecular weight molecule myoglobin negative negative band obtained optical activity ORD curve parameters partial specific volume particles peptide perturbation Phys Pilz plot polarized poly-L-proline polymer polypeptides positive procedure protein protein solution pulse Pysh radius of gyration random coil region residues rotational strength rotatory sample Schellman Section shape small-angle solvent spectra sphere studies subunits T₁ temperature theory Tinoco tion transition transition dipole moment tyrosine vector wavefunctions wavelength Woody X-ray zero