Physical Principles and Techniques of Protein Chemistry, Part 3Sydney J. Leach |
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Page 547
... tryptophan in water . The spectrum is very similar to that of N - acetyltryptophanamide in water ( Shiraki , 1969 ) , except that the intensities of the bands of the latter are somewhat lower and the amide shows a fourth band ( negative ...
... tryptophan in water . The spectrum is very similar to that of N - acetyltryptophanamide in water ( Shiraki , 1969 ) , except that the intensities of the bands of the latter are somewhat lower and the amide shows a fourth band ( negative ...
Page 548
... tryptophan basis , the ellipticity is 4300 deg- cm2 / dmole for poly - L - tryptophan , 2985 deg - cm2 / dmole for the copolymer of mole fraction 0.84 , and 1940 deg - cm2 / dmole for the copolymer of mole function 0.68 . The copolymer ...
... tryptophan basis , the ellipticity is 4300 deg- cm2 / dmole for poly - L - tryptophan , 2985 deg - cm2 / dmole for the copolymer of mole fraction 0.84 , and 1940 deg - cm2 / dmole for the copolymer of mole function 0.68 . The copolymer ...
Page 563
... tryptophan interactions dominate the spectrum and we must therefore anticipate a possibly complex set of ellipticity ... tryptophan residues , of the active site in the near - UV CD spectrum . The two longest wavelength bands are due to ...
... tryptophan interactions dominate the spectrum and we must therefore anticipate a possibly complex set of ellipticity ... tryptophan residues , of the active site in the near - UV CD spectrum . The two longest wavelength bands are due to ...
Contents
25 | 4 |
E The Isopotential Specific Volume | 10 |
Direct Volume Change | 22 |
Copyright | |
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a-helical a-helix absorption band acid angle B-structure Beychok Biochem Biochemistry Biol Blout c₂ calculated CD band CD spectrum Chem chromophore circular dichroism coefficient Cohn coil complex concentration conformation contribution Cotton effects creatine kinase cross-section denatured determined dipole Doty electron density ellipticity enzyme equation equilibrium exciton experimental factor Fasman function helical content helix intensity interaction kinase Kratky lysozyme magnetic measurements method Moffitt molecular weight molecule myoglobin negative negative band obtained optical activity ORD curve parameters partial specific volume particles peptide perturbation Phys Pilz plot polarized poly-L-proline polymer polypeptides positive procedure protein protein solution pulse Pysh radius of gyration random coil region residues rotational strength rotatory sample Schellman Section shape small-angle solvent spectra sphere studies subunits T₁ temperature theory Tinoco tion transition transition dipole moment tyrosine vector wavefunctions wavelength Woody X-ray zero