Polyelectrolytes |
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Page 5
... chain has one of four kinds of base . The degree of polymerization , i.e. , the number of monomers in a ... chain is about 2.5 Å in the first example of Fig . 1. Since the radius of each atom in the main chain is of the order of 1 Å ...
... chain has one of four kinds of base . The degree of polymerization , i.e. , the number of monomers in a ... chain is about 2.5 Å in the first example of Fig . 1. Since the radius of each atom in the main chain is of the order of 1 Å ...
Page 7
... chains , main chains , and solvent molecules or ions . The conformation of such a chain has two classifications , random coil and helix . In the random coil the series of rotation angles of successive bonds specifying the conformation ...
... chains , main chains , and solvent molecules or ions . The conformation of such a chain has two classifications , random coil and helix . In the random coil the series of rotation angles of successive bonds specifying the conformation ...
Page 137
... chain - like macromolecule . fluctuation is a characteristic property of linear macromolecules in the random coil conformation . The above equation shows that the fluctuation of the end - to - end distance under a constant external ...
... chain - like macromolecule . fluctuation is a characteristic property of linear macromolecules in the random coil conformation . The above equation shows that the fluctuation of the end - to - end distance under a constant external ...
Contents
Preface | 1 |
theoretically understandable Idealized treatment based on the simplest | 5 |
Electrical Potential Around the Macroion | 9 |
Copyright | |
19 other sections not shown
Common terms and phrases
activity coefficient additivity law alkali apparent charge bound counter ions chain Chapter charge density charged groups chemical potential coefficient of counter concentration of counter concentration of free concentration of macroions copolymer coulomb counter ion condensation critical value cylindrical macroion cylindrical model decreases degree of dissociation degree of neutralization derived dielectric constant dielectric increment electric free energy entropy equilibrium experimental extensive force fluctuation free counter ions free energy free volume hydrogen ions increase interaction ionic atmosphere ionized groups kinds of counter larger than unity logarithm monomers number of charges number of counter number of free osmotic coefficient osmotic pressure Poisson-Boltzmann equation polyacids polyacrylic acid polyelectrolytes Polymer polyvalent counter ions potential trough potential valley proportional radius random coil ratio refractive index region relation repulsion result rodlike macroion salt concentration shown in Fig simple salt smaller than unity sodium ions spherical macroion total number valence water structure