Polyelectrolytes |
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Page 24
... charge density corresponds to the saturated vapor pressure coexisting with the liquid . The counter ions in the volume of macroions correspond to the molecules in the liquid phase . Counter ion condensation is a characteristic ...
... charge density corresponds to the saturated vapor pressure coexisting with the liquid . The counter ions in the volume of macroions correspond to the molecules in the liquid phase . Counter ion condensation is a characteristic ...
Page 42
... charge density as long as charged groups can be repre- sented by a uniform charge density along the cylinder . It should be noted , however , that the radius of the ionic atomosphere around each multi- valent group is small so that ...
... charge density as long as charged groups can be repre- sented by a uniform charge density along the cylinder . It should be noted , however , that the radius of the ionic atomosphere around each multi- valent group is small so that ...
Page 96
... charge density to which the macroion was reduced by the binding of polyvalent counter ions . It is not necessary to take into consideration the direct correlation between two kinds of counter ions . In general , when the total number of ...
... charge density to which the macroion was reduced by the binding of polyvalent counter ions . It is not necessary to take into consideration the direct correlation between two kinds of counter ions . In general , when the total number of ...
Contents
Preface | 1 |
theoretically understandable Idealized treatment based on the simplest | 5 |
Electrical Potential Around the Macroion | 9 |
Copyright | |
19 other sections not shown
Common terms and phrases
activity coefficient additivity law alkali apparent charge bound counter ions chain Chapter charge density charged groups chemical potential coefficient of counter concentration of counter concentration of free concentration of macroions copolymer coulomb counter ion condensation critical value cylindrical macroion cylindrical model decreases degree of dissociation degree of neutralization derived dielectric constant dielectric increment electric free energy entropy equilibrium experimental extensive force fluctuation free counter ions free energy free volume hydrogen ions increase interaction ionic atmosphere ionized groups kinds of counter larger than unity logarithm monomers number of charges number of counter number of free osmotic coefficient osmotic pressure Poisson-Boltzmann equation polyacids polyacrylic acid polyelectrolytes Polymer polyvalent counter ions potential trough potential valley proportional radius random coil ratio refractive index region relation repulsion result rodlike macroion salt concentration shown in Fig simple salt smaller than unity sodium ions spherical macroion total number valence water structure