Polyelectrolytes |
From inside the book
Results 1-3 of 51
Page 15
... concentration . The value of ẞ is smaller for larger values of n or P. The number of free counter ions increases very slowly with n , as shown in Fig . 76. Equation ( 4 ) shows that for large values of P , the value of ßP or n * is ...
... concentration . The value of ẞ is smaller for larger values of n or P. The number of free counter ions increases very slowly with n , as shown in Fig . 76. Equation ( 4 ) shows that for large values of P , the value of ßP or n * is ...
Page 73
... concentration of free hydrogen ions is very much smaller than that of alkali ions . The number of localized hydrogen ions or the number of acid groups is much larger than the number of mobile hydrogen ions except at very low concentrations ...
... concentration of free hydrogen ions is very much smaller than that of alkali ions . The number of localized hydrogen ions or the number of acid groups is much larger than the number of mobile hydrogen ions except at very low concentrations ...
Page 111
... free energy , for example , is not completely eliminated even at high salt concentrations . This is discussed in some detail in a later chapter . The concentration ... concentration of free counter ions outside the macroion and the factor exp ...
... free energy , for example , is not completely eliminated even at high salt concentrations . This is discussed in some detail in a later chapter . The concentration ... concentration of free counter ions outside the macroion and the factor exp ...
Contents
Preface | 1 |
theoretically understandable Idealized treatment based on the simplest | 5 |
Electrical Potential Around the Macroion | 9 |
Copyright | |
19 other sections not shown
Common terms and phrases
activity coefficient additivity law alkali apparent charge bound counter ions chain Chapter charge density charged groups chemical potential coefficient of counter concentration of counter concentration of free concentration of macroions copolymer coulomb counter ion condensation critical value cylindrical macroion cylindrical model decreases degree of dissociation degree of neutralization derived dielectric constant dielectric increment electric free energy entropy equilibrium experimental extensive force fluctuation free counter ions free energy free volume hydrogen ions increase interaction ionic atmosphere ionized groups kinds of counter larger than unity logarithm monomers number of charges number of counter number of free osmotic coefficient osmotic pressure Poisson-Boltzmann equation polyacids polyacrylic acid polyelectrolytes Polymer polyvalent counter ions potential trough potential valley proportional radius random coil ratio refractive index region relation repulsion result rodlike macroion salt concentration shown in Fig simple salt smaller than unity sodium ions spherical macroion total number valence water structure