Polyelectrolytes |
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Page 23
Fumio Oosawa. centration of free counter ions , and the simple cylindrical model can adequately explain the experimental facts . The theoretical ... condensation to liquid takes 2. DISTRIBUTION OF COUNTER IONS 23 Counter Ion Condensation ...
Fumio Oosawa. centration of free counter ions , and the simple cylindrical model can adequately explain the experimental facts . The theoretical ... condensation to liquid takes 2. DISTRIBUTION OF COUNTER IONS 23 Counter Ion Condensation ...
Page 24
... condensation , the concentration of free counter ions above the critical value of the charge density corresponds to ... ion condensation is a characteristic phenomenon in poly- electrolytes . In comparison with the usual condensation ...
... condensation , the concentration of free counter ions above the critical value of the charge density corresponds to ... ion condensation is a characteristic phenomenon in poly- electrolytes . In comparison with the usual condensation ...
Page 42
... condensation takes place at a lower density of charges and a smaller number ... ion condensation is not influenced by the valence of each chaiged group on the macroion at a given value of the charge ... Counter Ions of Different Valences.
... condensation takes place at a lower density of charges and a smaller number ... ion condensation is not influenced by the valence of each chaiged group on the macroion at a given value of the charge ... Counter Ions of Different Valences.
Contents
Preface | 1 |
theoretically understandable Idealized treatment based on the simplest | 5 |
Electrical Potential Around the Macroion | 9 |
Copyright | |
19 other sections not shown
Common terms and phrases
activity coefficient additivity law alkali apparent charge bound counter ions chain Chapter charge density charged groups chemical potential coefficient of counter concentration of counter concentration of free concentration of macroions copolymer coulomb counter ion condensation critical value cylindrical macroion cylindrical model decreases degree of dissociation degree of neutralization derived dielectric constant dielectric increment electric free energy entropy equilibrium experimental extensive force fluctuation free counter ions free energy free volume hydrogen ions increase interaction ionic atmosphere ionized groups kinds of counter larger than unity logarithm monomers number of charges number of counter number of free osmotic coefficient osmotic pressure Poisson-Boltzmann equation polyacids polyacrylic acid polyelectrolytes Polymer polyvalent counter ions potential trough potential valley proportional radius random coil ratio refractive index region relation repulsion result rodlike macroion salt concentration shown in Fig simple salt smaller than unity sodium ions spherical macroion total number valence water structure