Polyelectrolytes |
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Page 45
... value of ( n * / n ) Q can not be less than 1 / z ' even at ẞ ' = 0. Therefore , the binding continues to increase ... critical value for their condensation . At this critical value , further addition begins to produce free counter ions ...
... value of ( n * / n ) Q can not be less than 1 / z ' even at ẞ ' = 0. Therefore , the binding continues to increase ... critical value for their condensation . At this critical value , further addition begins to produce free counter ions ...
Page 81
... critical concentration of sodium salt which depends on the degree of neutralization , as shown in Fig . 26b . Above ... value of the change of the refractive index at critical points dependent on the degree of neutralization is in good ...
... critical concentration of sodium salt which depends on the degree of neutralization , as shown in Fig . 26b . Above ... value of the change of the refractive index at critical points dependent on the degree of neutralization is in good ...
Page 96
... critical value and no monovalent counter ions are bound . Therefore , the addition of monovalent salts does not change the effective charge or number of condensed ions . Let us next consider a mixture of two kinds of monovalent counter ...
... critical value and no monovalent counter ions are bound . Therefore , the addition of monovalent salts does not change the effective charge or number of condensed ions . Let us next consider a mixture of two kinds of monovalent counter ...
Contents
Preface | 1 |
theoretically understandable Idealized treatment based on the simplest | 5 |
Electrical Potential Around the Macroion | 9 |
Copyright | |
19 other sections not shown
Common terms and phrases
activity coefficient additivity law alkali apparent charge bound counter ions chain Chapter charge density charged groups chemical potential coefficient of counter concentration of counter concentration of free concentration of macroions copolymer coulomb counter ion condensation critical value cylindrical macroion cylindrical model decreases degree of dissociation degree of neutralization derived dielectric constant dielectric increment electric free energy entropy equilibrium experimental extensive force fluctuation free counter ions free energy free volume hydrogen ions increase interaction ionic atmosphere ionized groups kinds of counter larger than unity logarithm monomers number of charges number of counter number of free osmotic coefficient osmotic pressure Poisson-Boltzmann equation polyacids polyacrylic acid polyelectrolytes Polymer polyvalent counter ions potential trough potential valley proportional radius random coil ratio refractive index region relation repulsion result rodlike macroion salt concentration shown in Fig simple salt smaller than unity sodium ions spherical macroion total number valence water structure