Polyelectrolytes |
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Page 9
Fumio Oosawa. IV . ELECTRICAL POTENTIAL AROUND THE MACROION Let us consider a macroion in the spherical random coil ... cylindrical macroion with charged groups . ( d ) The potential profiles along the lines crossing the volume occupied ...
Fumio Oosawa. IV . ELECTRICAL POTENTIAL AROUND THE MACROION Let us consider a macroion in the spherical random coil ... cylindrical macroion with charged groups . ( d ) The potential profiles along the lines crossing the volume occupied ...
Page 22
... cylindrical region along the macroion . In the above model the degree of dissociation and the activity are determined by the quantity Q or d , the charge density on the macroion , and are independent of the total number of charges ...
... cylindrical region along the macroion . In the above model the degree of dissociation and the activity are determined by the quantity Q or d , the charge density on the macroion , and are independent of the total number of charges ...
Page 131
... macroions . II . EXTENSIVE FORCE OF CYLINDRICAL MACROIONS In the cylindrical case , the extensive forces are different along the long axis , F and perpendicular to this axis , F. Each force is composed of two parts as before . One is ...
... macroions . II . EXTENSIVE FORCE OF CYLINDRICAL MACROIONS In the cylindrical case , the extensive forces are different along the long axis , F and perpendicular to this axis , F. Each force is composed of two parts as before . One is ...
Contents
Preface | 1 |
theoretically understandable Idealized treatment based on the simplest | 5 |
Electrical Potential Around the Macroion | 9 |
Copyright | |
17 other sections not shown
Common terms and phrases
absence of salt activity coefficient activity of counter addition of salt additivity law alkali apparent charge average bound counter ions chain Chapter charge density charged groups chemical potential coefficient of counter concentration of counter concentration of free concentration of macroions copolymer counter ion condensation critical value cylindrical macroion decreases degree of dissociation degree of neutralization density Q derived dielectric constant dielectric increment electric free energy electric potential entropy equilibrium experimental extensive force fluctuation free counter ions free energy free volume hydrogen ions increase interaction ionized groups kinds of counter macromolecules monomers monovalent number of charged number of counter number of free osmotic coefficient osmotic pressure Poisson-Boltzmann equation polyacids polyacrylic acid polyelectrolytes polyvalent counter ions proportional radius random coil ratio refractive index region relation result rodlike macroions rods salt concentration salt solution shown in Fig simple salt small ions sodium ions spherical macroion total number valence