## Polyelectrolytes |

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Page 16

(a) Relations of the apparent

activity coefficient of counter ions y to the apparent volume concentration <j> at

various values of the charge density P in solutions of spherical macroions. (1) P =

8 ...

(a) Relations of the apparent

**degree of dissociation**of counter ions 0 and theactivity coefficient of counter ions y to the apparent volume concentration <j> at

various values of the charge density P in solutions of spherical macroions. (1) P =

8 ...

Page 41

The equation of the distribution equilibrium between counter ions in the simple

two phase model is written: In (1 -flip = In 0/(1 - 4>) - ze05^/kT (66) where /?, as

before, is the apparent

charge ...

The equation of the distribution equilibrium between counter ions in the simple

two phase model is written: In (1 -flip = In 0/(1 - 4>) - ze05^/kT (66) where /?, as

before, is the apparent

**degree of dissociation**, i.e., the ratio of the apparentcharge ...

Page 43

the assumption that z' is larger than z, it is convenient to classify the value of Q

into the following four categories for analysis of the behavior of P and P' at infinite

dilution. The

the assumption that z' is larger than z, it is convenient to classify the value of Q

into the following four categories for analysis of the behavior of P and P' at infinite

dilution. The

**degree of dissociation**tends to different values determined by the ...### What people are saying - Write a review

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### Contents

Preface | 1 |

theoretically understandable Idealized treatment based on the simplest | 5 |

Electrical Potential Around the Macroion | 9 |

Copyright | |

17 other sections not shown

### Common terms and phrases

absence of salt activity coefficient activity of counter addition of salt additivity law alkali apparent charge bound counter ions chain Chapter charge density charged groups chemical potential coefficient of counter coil conformation concentration of counter concentration of free concentration of macroions copolymer counter ion condensation critical value cylindrical macroion decreases degree of dissociation degree of neutralization density Q derived dielectric constant dielectric dispersion dielectric increment electric free energy entropy equilibrium experimental extensive force fluctuation free counter ions free energy free volume hydrogen ions increase interaction ionized groups kinds of counter macromolecules monomers monovalent number of charged number of counter number of free osmotic coefficient osmotic pressure Poisson-Boltzmann equation polyacids polyacrylic acid polyelectrolytes polyvalent counter ions potential valley proportional radius random coil ratio refractive index region relation result rodlike macroions rods salt concentration salt solution shown in Fig simple salt small ions sodium ions spherical macroion total number valence