Polyelectrolytes |
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Page 16
... degree of dissociation ẞ ( 1 ) . ( b ) Relations of the apparent degree of dissociation ẞ or the number of the effective charge n * to the charge density P or the total number of charged groups n at various concentrations c , of ...
... degree of dissociation ẞ ( 1 ) . ( b ) Relations of the apparent degree of dissociation ẞ or the number of the effective charge n * to the charge density P or the total number of charged groups n at various concentrations c , of ...
Page 43
... degree of dissociation tends to different values determined by the value of Q. В B → 1 and B ' → 1 for 0 ≤ 1 / z ... dissociation of counter ions of the larger valence z ' begins to be suppressed at Q = 1 / z ' . This critical value ...
... degree of dissociation tends to different values determined by the value of Q. В B → 1 and B ' → 1 for 0 ≤ 1 / z ... dissociation of counter ions of the larger valence z ' begins to be suppressed at Q = 1 / z ' . This critical value ...
Page 45
... degree of dissociation of counter ions of valence z ' must be equal to zero at Q larger than 1 / qz ' . During decrease of the degree of dissociation of counter ions of higher valence from unity to zero , all of the counter ions of ...
... degree of dissociation of counter ions of valence z ' must be equal to zero at Q larger than 1 / qz ' . During decrease of the degree of dissociation of counter ions of higher valence from unity to zero , all of the counter ions of ...
Contents
Preface | 1 |
theoretically understandable Idealized treatment based on the simplest | 5 |
Electrical Potential Around the Macroion | 9 |
Copyright | |
19 other sections not shown
Common terms and phrases
activity coefficient additivity law alkali apparent charge bound counter ions chain Chapter charge density charged groups chemical potential coefficient of counter concentration of counter concentration of free concentration of macroions copolymer coulomb counter ion condensation critical value cylindrical macroion cylindrical model decreases degree of dissociation degree of neutralization derived dielectric constant dielectric increment electric free energy entropy equilibrium experimental extensive force fluctuation free counter ions free energy free volume hydrogen ions increase interaction ionic atmosphere ionized groups kinds of counter larger than unity logarithm monomers number of charges number of counter number of free osmotic coefficient osmotic pressure Poisson-Boltzmann equation polyacids polyacrylic acid polyelectrolytes Polymer polyvalent counter ions potential trough potential valley proportional radius random coil ratio refractive index region relation repulsion result rodlike macroion salt concentration shown in Fig simple salt smaller than unity sodium ions spherical macroion total number valence water structure