Polyelectrolytes |
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Page 77
... degree of neutralization , i.e. , to the amount of the base added at a constant concentration of the acid , as shown in Fig . 24a . In the case of the neutralization of strong acid this decrement of the index is associated with the ...
... degree of neutralization , i.e. , to the amount of the base added at a constant concentration of the acid , as shown in Fig . 24a . In the case of the neutralization of strong acid this decrement of the index is associated with the ...
Page 81
... degree of neutralization a is given in Fig . 26a . In the next experiment , sodium ions are added to solutions of polyacid neutralized by tetrabutylammonium hydroxide to various degrees . Upon the addition of sodium salt , the ...
... degree of neutralization a is given in Fig . 26a . In the next experiment , sodium ions are added to solutions of polyacid neutralized by tetrabutylammonium hydroxide to various degrees . Upon the addition of sodium salt , the ...
Page 108
... degree of neutralization in Fig . 32b . The value of the derivative [ ~ ( y , ca ) / dca ] or [ d ( y , α ) / dα ] estimated from the gradient by the use of Eq . ( 177 ) is also given in the same figure . At high degrees of neutralization ...
... degree of neutralization in Fig . 32b . The value of the derivative [ ~ ( y , ca ) / dca ] or [ d ( y , α ) / dα ] estimated from the gradient by the use of Eq . ( 177 ) is also given in the same figure . At high degrees of neutralization ...
Contents
Preface | 1 |
theoretically understandable Idealized treatment based on the simplest | 5 |
Electrical Potential Around the Macroion | 9 |
Copyright | |
19 other sections not shown
Common terms and phrases
activity coefficient additivity law alkali apparent charge bound counter ions chain Chapter charge density charged groups chemical potential coefficient of counter concentration of counter concentration of free concentration of macroions copolymer coulomb counter ion condensation critical value cylindrical macroion cylindrical model decreases degree of dissociation degree of neutralization derived dielectric constant dielectric increment electric free energy entropy equilibrium experimental extensive force fluctuation free counter ions free energy free volume hydrogen ions increase interaction ionic atmosphere ionized groups kinds of counter larger than unity logarithm monomers number of charges number of counter number of free osmotic coefficient osmotic pressure Poisson-Boltzmann equation polyacids polyacrylic acid polyelectrolytes Polymer polyvalent counter ions potential trough potential valley proportional radius random coil ratio refractive index region relation repulsion result rodlike macroion salt concentration shown in Fig simple salt smaller than unity sodium ions spherical macroion total number valence water structure