Polyelectrolytes |
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Page 59
... fluctuation dc ( x ) must vanish since the average distribution is an equilibrium one . The electric dipole produced by the fluctuation dc + ( x ) is given by μ = eos ( x - 1 / 2 ) 8c + ( x ) dx ( 99 ) Here , as shown in Fig . 19 , the ...
... fluctuation dc ( x ) must vanish since the average distribution is an equilibrium one . The electric dipole produced by the fluctuation dc + ( x ) is given by μ = eos ( x - 1 / 2 ) 8c + ( x ) dx ( 99 ) Here , as shown in Fig . 19 , the ...
Page 122
... fluctuation consequently increases . The ratio Ysocso / Ypcp determines the effect of salt on the fluctuation and the increase of the fluctuation occurs according to the square of this ratio . Therefore in the range of pcp / Ysocso 1 ...
... fluctuation consequently increases . The ratio Ysocso / Ypcp determines the effect of salt on the fluctuation and the increase of the fluctuation occurs according to the square of this ratio . Therefore in the range of pcp / Ysocso 1 ...
Page 137
... Fluctuation of the end - to - end distance of a linear chain - like macromolecule . fluctuation is a characteristic property of linear macromolecules in the random coil conformation . The above equation shows that the fluctuation of the ...
... Fluctuation of the end - to - end distance of a linear chain - like macromolecule . fluctuation is a characteristic property of linear macromolecules in the random coil conformation . The above equation shows that the fluctuation of the ...
Contents
Preface | 1 |
theoretically understandable Idealized treatment based on the simplest | 5 |
Electrical Potential Around the Macroion | 9 |
Copyright | |
19 other sections not shown
Common terms and phrases
activity coefficient additivity law alkali apparent charge bound counter ions chain Chapter charge density charged groups chemical potential coefficient of counter concentration of counter concentration of free concentration of macroions copolymer coulomb counter ion condensation critical value cylindrical macroion cylindrical model decreases degree of dissociation degree of neutralization derived dielectric constant dielectric increment electric free energy entropy equilibrium experimental extensive force fluctuation free counter ions free energy free volume hydrogen ions increase interaction ionic atmosphere ionized groups kinds of counter larger than unity logarithm monomers number of charges number of counter number of free osmotic coefficient osmotic pressure Poisson-Boltzmann equation polyacids polyacrylic acid polyelectrolytes Polymer polyvalent counter ions potential trough potential valley proportional radius random coil ratio refractive index region relation repulsion result rodlike macroion salt concentration shown in Fig simple salt smaller than unity sodium ions spherical macroion total number valence water structure