## Polyelectrolytes |

### From inside the book

Results 1-3 of 52

Page 25

occupied by the apparent

the

occupied by the apparent

**volume**of the macroions and the region outside of this**volume**. ... with each other only at short distance, the energy difference betweenthe

**free**state and the bound state is independent of the**volume**of the**free**space.Page 31

This is directly derived from Eq. (16) and also confirmed by differentiation of the

free energy, Eq. (22), with respect to the number of counter ions. ... The

equal.

This is directly derived from Eq. (16) and also confirmed by differentiation of the

free energy, Eq. (22), with respect to the number of counter ions. ... The

**free****volume**of each macroion in which electroneutrality is satisfied is not necessarilyequal.

Page 103

In the absence of salt the free energy / of polyelectrolyte solution per macroion

with its counter ions is given by ... In the differentiation it must be remembered

that the free energy/is a function of N through the size of the

In the absence of salt the free energy / of polyelectrolyte solution per macroion

with its counter ions is given by ... In the differentiation it must be remembered

that the free energy/is a function of N through the size of the

**free volume**of the ...### What people are saying - Write a review

We haven't found any reviews in the usual places.

### Contents

Preface | 1 |

theoretically understandable Idealized treatment based on the simplest | 5 |

Electrical Potential Around the Macroion | 9 |

Copyright | |

17 other sections not shown

### Common terms and phrases

absence of salt activity coefficient activity of counter addition of salt additivity law alkali apparent charge bound counter ions chain Chapter charge density charged groups chemical potential coefficient of counter coil conformation concentration of counter concentration of free concentration of macroions copolymer counter ion condensation critical value cylindrical macroion decreases degree of dissociation degree of neutralization density Q derived dielectric constant dielectric dispersion dielectric increment electric free energy entropy equilibrium experimental extensive force fluctuation free counter ions free energy free volume hydrogen ions increase interaction ionized groups kinds of counter macromolecules monomers monovalent number of charged number of counter number of free osmotic coefficient osmotic pressure Poisson-Boltzmann equation polyacids polyacrylic acid polyelectrolytes polyvalent counter ions potential valley proportional radius random coil ratio refractive index region relation result rodlike macroions rods salt concentration salt solution shown in Fig simple salt small ions sodium ions spherical macroion total number valence