Polyelectrolytes |
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Page 1
... macromolecules , the morphology of polyvalent macroions is one of the central problems of polyelectrolytes . Most of the macroions are long flexible chains having a large extension in solution . Their size and shape depend on the charge ...
... macromolecules , the morphology of polyvalent macroions is one of the central problems of polyelectrolytes . Most of the macroions are long flexible chains having a large extension in solution . Their size and shape depend on the charge ...
Page 105
... macromolecules in different states . The chemical potential of macromolecules in a state having a strong affinity for small molecules is decreased to a large extent by addition of such small molecules ( 54 ) . If a repulsive force acts ...
... macromolecules in different states . The chemical potential of macromolecules in a state having a strong affinity for small molecules is decreased to a large extent by addition of such small molecules ( 54 ) . If a repulsive force acts ...
Page 137
... macromolecule . fluctuation is a characteristic property of linear macromolecules in the random coil conformation . The above equation shows that the fluctuation of the end - to - end distance under a constant external force is ...
... macromolecule . fluctuation is a characteristic property of linear macromolecules in the random coil conformation . The above equation shows that the fluctuation of the end - to - end distance under a constant external force is ...
Contents
Preface | 1 |
theoretically understandable Idealized treatment based on the simplest | 5 |
Electrical Potential Around the Macroion | 9 |
Copyright | |
17 other sections not shown
Common terms and phrases
absence of salt activity coefficient activity of counter addition of salt additivity law alkali apparent charge average bound counter ions chain Chapter charge density charged groups chemical potential coefficient of counter concentration of counter concentration of free concentration of macroions copolymer counter ion condensation critical value cylindrical macroion decreases degree of dissociation degree of neutralization density Q derived dielectric constant dielectric increment electric free energy electric potential entropy equilibrium experimental extensive force fluctuation free counter ions free energy free volume hydrogen ions increase interaction ionized groups kinds of counter macromolecules monomers monovalent number of charged number of counter number of free osmotic coefficient osmotic pressure Poisson-Boltzmann equation polyacids polyacrylic acid polyelectrolytes polyvalent counter ions proportional radius random coil ratio refractive index region relation result rodlike macroions rods salt concentration salt solution shown in Fig simple salt small ions sodium ions spherical macroion total number valence