Polyelectrolytes |
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Page 3
... monomers , vinyl alcohol and acrylic acid . The latter monomer is charged by the addition of a sufficient amount of alkali . The number of charges per macroion is regulated by the ratio of the two kinds of monomer in the copolymer . In ...
... monomers , vinyl alcohol and acrylic acid . The latter monomer is charged by the addition of a sufficient amount of alkali . The number of charges per macroion is regulated by the ratio of the two kinds of monomer in the copolymer . In ...
Page 136
... monomers , and b is the length of the monomer ; mb is consequently the length of the fully stretched macroion . If the rotation of monomers in the macroion is restricted to a certain extent , it is convenient to choose the quantities m ...
... monomers , and b is the length of the monomer ; mb is consequently the length of the fully stretched macroion . If the rotation of monomers in the macroion is restricted to a certain extent , it is convenient to choose the quantities m ...
Page 155
... monomers . nN / V , the total number concentration of charged groups or counter ions . The number concentration of alkali . = The number concentration of the simple salt added . The number concentration of solvent molecules . The number ...
... monomers . nN / V , the total number concentration of charged groups or counter ions . The number concentration of alkali . = The number concentration of the simple salt added . The number concentration of solvent molecules . The number ...
Contents
Preface | 1 |
theoretically understandable Idealized treatment based on the simplest | 5 |
Electrical Potential Around the Macroion | 9 |
Copyright | |
17 other sections not shown
Common terms and phrases
absence of salt activity coefficient activity of counter addition of salt additivity law alkali apparent charge average bound counter ions chain Chapter charge density charged groups chemical potential coefficient of counter concentration of counter concentration of free concentration of macroions copolymer counter ion condensation critical value cylindrical macroion decreases degree of dissociation degree of neutralization density Q derived dielectric constant dielectric increment electric free energy electric potential entropy equilibrium experimental extensive force fluctuation free counter ions free energy free volume hydrogen ions increase interaction ionized groups kinds of counter macromolecules monomers monovalent number of charged number of counter number of free osmotic coefficient osmotic pressure Poisson-Boltzmann equation polyacids polyacrylic acid polyelectrolytes polyvalent counter ions proportional radius random coil ratio refractive index region relation result rodlike macroions rods salt concentration salt solution shown in Fig simple salt small ions sodium ions spherical macroion total number valence