Polyelectrolytes |
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Page 23
... total concentration of macroions in the solution . An increasing number of counter ions are distributed inside and outside of volumes occupied by macroions . When the number of charges and counter ions is small , counter ions are ...
... total concentration of macroions in the solution . An increasing number of counter ions are distributed inside and outside of volumes occupied by macroions . When the number of charges and counter ions is small , counter ions are ...
Page 24
... charge density of macroions , or the total number of counter ions , or the total number of molecules . ( — ) : The number of free counter ions or the density of the gas phase ; ( —— ) : the number of bound counter ions or the amount of ...
... charge density of macroions , or the total number of counter ions , or the total number of molecules . ( — ) : The number of free counter ions or the density of the gas phase ; ( —— ) : the number of bound counter ions or the amount of ...
Page 72
... number of localized counter ions to the total number of counter ions ) is given by n " / n . If localized binding can take place on charged groups of the macroion at random , the equilibrium condition between localized and bound but ...
... number of localized counter ions to the total number of counter ions ) is given by n " / n . If localized binding can take place on charged groups of the macroion at random , the equilibrium condition between localized and bound but ...
Contents
Preface | 1 |
theoretically understandable Idealized treatment based on the simplest | 5 |
Electrical Potential Around the Macroion | 9 |
Copyright | |
19 other sections not shown
Common terms and phrases
activity coefficient additivity law alkali apparent charge bound counter ions chain Chapter charge density charged groups chemical potential coefficient of counter concentration of counter concentration of free concentration of macroions copolymer coulomb counter ion condensation critical value cylindrical macroion cylindrical model decreases degree of dissociation degree of neutralization derived dielectric constant dielectric increment electric free energy entropy equilibrium experimental extensive force fluctuation free counter ions free energy free volume hydrogen ions increase interaction ionic atmosphere ionized groups kinds of counter larger than unity logarithm monomers number of charges number of counter number of free osmotic coefficient osmotic pressure Poisson-Boltzmann equation polyacids polyacrylic acid polyelectrolytes Polymer polyvalent counter ions potential trough potential valley proportional radius random coil ratio refractive index region relation repulsion result rodlike macroion salt concentration shown in Fig simple salt smaller than unity sodium ions spherical macroion total number valence water structure