## Polyelectrolytes |

### From inside the book

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Page 23

centration of free counter ions, and the simple cylindrical model can adequately

explain the experimental facts. ... An increasing

distributed inside and outside of volumes occupied by macroions. When the

number of ...

centration of free counter ions, and the simple cylindrical model can adequately

explain the experimental facts. ... An increasing

**number of counter**ions aredistributed inside and outside of volumes occupied by macroions. When the

number of ...

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volume of the gas, the condensation to liquid takes place at a certain critical

value of the number or the density of gas ... The abscissa is the charge density of

macroions, or the total

volume of the gas, the condensation to liquid takes place at a certain critical

value of the number or the density of gas ... The abscissa is the charge density of

macroions, or the total

**number of counter**ions, or the total number of molecules.Page 72

The average concentration of bound but mobile counter ions in v is given by n'/v.

The degree of localized binding (the ratio of the number of localized counter ions

to the total

The average concentration of bound but mobile counter ions in v is given by n'/v.

The degree of localized binding (the ratio of the number of localized counter ions

to the total

**number of counter**ions) is given by n"/n. If localized binding can take ...### What people are saying - Write a review

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### Contents

Preface | 1 |

theoretically understandable Idealized treatment based on the simplest | 5 |

Electrical Potential Around the Macroion | 9 |

Copyright | |

17 other sections not shown

### Common terms and phrases

absence of salt activity coefficient activity of counter addition of salt additivity law alkali apparent charge bound counter ions chain Chapter charge density charged groups chemical potential coefficient of counter coil conformation concentration of counter concentration of free concentration of macroions copolymer counter ion condensation critical value cylindrical macroion decreases degree of dissociation degree of neutralization density Q derived dielectric constant dielectric dispersion dielectric increment electric free energy entropy equilibrium experimental extensive force fluctuation free counter ions free energy free volume hydrogen ions increase interaction ionized groups kinds of counter macromolecules monomers monovalent number of charged number of counter number of free osmotic coefficient osmotic pressure Poisson-Boltzmann equation polyacids polyacrylic acid polyelectrolytes polyvalent counter ions potential valley proportional radius random coil ratio refractive index region relation result rodlike macroions rods salt concentration salt solution shown in Fig simple salt small ions sodium ions spherical macroion total number valence