Polyelectrolytes |
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Page 23
... number of hydrogen ions and hydroxyl ions in water becomes significant . IV . COUNTER ION CONDENSATION The previous section has made clear one of the characteristic properties of ... COUNTER IONS 23 Counter Ion Condensation 3473.
... number of hydrogen ions and hydroxyl ions in water becomes significant . IV . COUNTER ION CONDENSATION The previous section has made clear one of the characteristic properties of ... COUNTER IONS 23 Counter Ion Condensation 3473.
Page 24
... number or the density of gas molecules . Above this critical point the increase of the number of molecules does not ... counter ions above the critical value of the charge density corresponds to the saturated vapor pressure coexisting with ...
... number or the density of gas molecules . Above this critical point the increase of the number of molecules does not ... counter ions above the critical value of the charge density corresponds to the saturated vapor pressure coexisting with ...
Page 72
... number of localized counter ions to the total number of counter ions ) is given by n " / n . If localized binding can take place on charged groups of the macroion at random , the equilibrium condition between localized and bound but ...
... number of localized counter ions to the total number of counter ions ) is given by n " / n . If localized binding can take place on charged groups of the macroion at random , the equilibrium condition between localized and bound but ...
Contents
Preface | 1 |
theoretically understandable Idealized treatment based on the simplest | 5 |
Electrical Potential Around the Macroion | 9 |
Copyright | |
19 other sections not shown
Common terms and phrases
activity coefficient additivity law alkali apparent charge bound counter ions chain Chapter charge density charged groups chemical potential coefficient of counter concentration of counter concentration of free concentration of macroions copolymer coulomb counter ion condensation critical value cylindrical macroion cylindrical model decreases degree of dissociation degree of neutralization derived dielectric constant dielectric increment electric free energy entropy equilibrium experimental extensive force fluctuation free counter ions free energy free volume hydrogen ions increase interaction ionic atmosphere ionized groups kinds of counter larger than unity logarithm monomers number of charges number of counter number of free osmotic coefficient osmotic pressure Poisson-Boltzmann equation polyacids polyacrylic acid polyelectrolytes Polymer polyvalent counter ions potential trough potential valley proportional radius random coil ratio refractive index region relation repulsion result rodlike macroion salt concentration shown in Fig simple salt smaller than unity sodium ions spherical macroion total number valence water structure