Polyelectrolytes |
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Page 24
... number or the density of gas molecules . Above this critical point the ... free counter ions above the critical value of the charge density corresponds ... number of counter ions , or the total number of molecules . ( — ) : The number of ...
... number or the density of gas molecules . Above this critical point the ... free counter ions above the critical value of the charge density corresponds ... number of counter ions , or the total number of molecules . ( — ) : The number of ...
Page 25
... number of free counter ions is too large to establish equilibrium between two phases . Then , some of the free counter ions are forced to enter into the bound state . This flow of counter ions from the free state to the bound state can ...
... number of free counter ions is too large to establish equilibrium between two phases . Then , some of the free counter ions are forced to enter into the bound state . This flow of counter ions from the free state to the bound state can ...
Page 42
... number of free counter ions . The critical value of the charge density is determined by the balance between the entropy and energy difference of bound and free counter ions . In the two - phase approximation , counter ion condensation ...
... number of free counter ions . The critical value of the charge density is determined by the balance between the entropy and energy difference of bound and free counter ions . In the two - phase approximation , counter ion condensation ...
Contents
Preface | 1 |
theoretically understandable Idealized treatment based on the simplest | 5 |
Electrical Potential Around the Macroion | 9 |
Copyright | |
19 other sections not shown
Common terms and phrases
activity coefficient additivity law alkali apparent charge bound counter ions chain Chapter charge density charged groups chemical potential coefficient of counter concentration of counter concentration of free concentration of macroions copolymer coulomb counter ion condensation critical value cylindrical macroion cylindrical model decreases degree of dissociation degree of neutralization derived dielectric constant dielectric increment electric free energy entropy equilibrium experimental extensive force fluctuation free counter ions free energy free volume hydrogen ions increase interaction ionic atmosphere ionized groups kinds of counter larger than unity logarithm monomers number of charges number of counter number of free osmotic coefficient osmotic pressure Poisson-Boltzmann equation polyacids polyacrylic acid polyelectrolytes Polymer polyvalent counter ions potential trough potential valley proportional radius random coil ratio refractive index region relation repulsion result rodlike macroion salt concentration shown in Fig simple salt smaller than unity sodium ions spherical macroion total number valence water structure