Polyelectrolytes |
From inside the book
Results 1-3 of 27
Page 97
... osmotic pressure of the mixture . As mentioned in the previous section , however , counter ions of smaller size are bound more than those of larger size . Therefore , the additivity law can ... Osmotic Pressure against Salt Solutions 88855.
... osmotic pressure of the mixture . As mentioned in the previous section , however , counter ions of smaller size are bound more than those of larger size . Therefore , the additivity law can ... Osmotic Pressure against Salt Solutions 88855.
Page 98
... osmotic equilibrium with a salt solution of concentration c , o , the ... pressure II ' of the solution of macroions against the salt solution is ... osmotic pressure can be solved as a function of concentrations c , and c 、 o . In the ...
... osmotic equilibrium with a salt solution of concentration c , o , the ... pressure II ' of the solution of macroions against the salt solution is ... osmotic pressure can be solved as a function of concentrations c , and c 、 o . In the ...
Page 130
... osmotic pressure of counter ions bound in v exceeds the contribution due to coulomb repulsion of the apparent charge when the concentration or the charge of the macroion increases . Such situation has been pointed out in several ...
... osmotic pressure of counter ions bound in v exceeds the contribution due to coulomb repulsion of the apparent charge when the concentration or the charge of the macroion increases . Such situation has been pointed out in several ...
Contents
Preface | 1 |
theoretically understandable Idealized treatment based on the simplest | 5 |
Electrical Potential Around the Macroion | 9 |
Copyright | |
19 other sections not shown
Common terms and phrases
activity coefficient additivity law alkali apparent charge bound counter ions chain Chapter charge density charged groups chemical potential coefficient of counter concentration of counter concentration of free concentration of macroions copolymer coulomb counter ion condensation critical value cylindrical macroion cylindrical model decreases degree of dissociation degree of neutralization derived dielectric constant dielectric increment electric free energy entropy equilibrium experimental extensive force fluctuation free counter ions free energy free volume hydrogen ions increase interaction ionic atmosphere ionized groups kinds of counter larger than unity logarithm monomers number of charges number of counter number of free osmotic coefficient osmotic pressure Poisson-Boltzmann equation polyacids polyacrylic acid polyelectrolytes Polymer polyvalent counter ions potential trough potential valley proportional radius random coil ratio refractive index region relation repulsion result rodlike macroion salt concentration shown in Fig simple salt smaller than unity sodium ions spherical macroion total number valence water structure