Polyelectrolytes |
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Page vi
... Macroions 103 II . Hydrogen Ion Equilibrium in the Presence of Salts III . The Electric Potential at the Macroion 106 110 9. Interaction Between Macroions 113 I. Interaction between Parallel Rodlike Macroions II . Extensive Force of an ...
... Macroions 103 II . Hydrogen Ion Equilibrium in the Presence of Salts III . The Electric Potential at the Macroion 106 110 9. Interaction Between Macroions 113 I. Interaction between Parallel Rodlike Macroions II . Extensive Force of an ...
Page 55
... macroion ; rodlike macroions give very much larger increment than spherical macroions , as shown in Fig . 15 ( 21 ) . Moreover , the dielectric increment due to rodlike macroions was found to increase rapidly with increasing length of the ...
... macroion ; rodlike macroions give very much larger increment than spherical macroions , as shown in Fig . 15 ( 21 ) . Moreover , the dielectric increment due to rodlike macroions was found to increase rapidly with increasing length of the ...
Page 113
Fumio Oosawa. Chapter 9 INTERACTION BETWEEN MACROIONS I. INTERACTION BETWEEN PARallel RodlikE MACROIONS Repulsion is expected between macroions of the same charge . It is depressed by counter ions accumulated in the neighborhood of these ...
Fumio Oosawa. Chapter 9 INTERACTION BETWEEN MACROIONS I. INTERACTION BETWEEN PARallel RodlikE MACROIONS Repulsion is expected between macroions of the same charge . It is depressed by counter ions accumulated in the neighborhood of these ...
Contents
Preface | 1 |
theoretically understandable Idealized treatment based on the simplest | 5 |
Electrical Potential Around the Macroion | 9 |
Copyright | |
19 other sections not shown
Common terms and phrases
activity coefficient additivity law alkali apparent charge bound counter ions chain Chapter charge density charged groups chemical potential coefficient of counter concentration of counter concentration of free concentration of macroions copolymer coulomb counter ion condensation critical value cylindrical macroion cylindrical model decreases degree of dissociation degree of neutralization derived dielectric constant dielectric increment electric free energy entropy equilibrium experimental extensive force fluctuation free counter ions free energy free volume hydrogen ions increase interaction ionic atmosphere ionized groups kinds of counter larger than unity logarithm monomers number of charges number of counter number of free osmotic coefficient osmotic pressure Poisson-Boltzmann equation polyacids polyacrylic acid polyelectrolytes Polymer polyvalent counter ions potential trough potential valley proportional radius random coil ratio refractive index region relation repulsion result rodlike macroion salt concentration shown in Fig simple salt smaller than unity sodium ions spherical macroion total number valence water structure