Polyelectrolytes |
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Page 97
... salt of counter ions of smaller size is added to a solution of macroions with counter ions of larger size , bound counter ions must be exchanged . IV . OSMOTIC PRESSURE Against SalT SOLUTIONS Equation ( 138 ) is rewritten as Π ПI = П ...
... salt of counter ions of smaller size is added to a solution of macroions with counter ions of larger size , bound counter ions must be exchanged . IV . OSMOTIC PRESSURE Against SalT SOLUTIONS Equation ( 138 ) is rewritten as Π ПI = П ...
Page 98
... salt c , in the solution of macroions is given as a function of the concentration of macroions and of the salt outside . The osmotic pressure ПI ' of the solution of macroions against the salt solution is given from Eq . ( 148 ) by ПI ...
... salt c , in the solution of macroions is given as a function of the concentration of macroions and of the salt outside . The osmotic pressure ПI ' of the solution of macroions against the salt solution is given from Eq . ( 148 ) by ПI ...
Page 105
... salt ions is replaced by its average over the entire range of the salt ... solution of macromolecules . Small molecules are assumed to have different ... salt to macro- ions ( with their counter ions ) increases the chemical potential of ...
... salt ions is replaced by its average over the entire range of the salt ... solution of macromolecules . Small molecules are assumed to have different ... salt to macro- ions ( with their counter ions ) increases the chemical potential of ...
Contents
Preface | 1 |
theoretically understandable Idealized treatment based on the simplest | 5 |
Electrical Potential Around the Macroion | 9 |
Copyright | |
17 other sections not shown
Common terms and phrases
absence of salt activity coefficient activity of counter addition of salt additivity law alkali apparent charge average bound counter ions chain Chapter charge density charged groups chemical potential coefficient of counter concentration of counter concentration of free concentration of macroions copolymer counter ion condensation critical value cylindrical macroion decreases degree of dissociation degree of neutralization density Q derived dielectric constant dielectric increment electric free energy electric potential entropy equilibrium experimental extensive force fluctuation free counter ions free energy free volume hydrogen ions increase interaction ionized groups kinds of counter macromolecules monomers monovalent number of charged number of counter number of free osmotic coefficient osmotic pressure Poisson-Boltzmann equation polyacids polyacrylic acid polyelectrolytes polyvalent counter ions proportional radius random coil ratio refractive index region relation result rodlike macroions rods salt concentration salt solution shown in Fig simple salt small ions sodium ions spherical macroion total number valence