Polyelectrolytes |
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Page 9
Fumio Oosawa. IV . ELECTRICAL POTENTIAL AROUND THE MACROION Let us consider a macroion in the spherical random coil conformation . Many discrete charges are distributed on the macroion as shown in Fig . 4a . Each of them is the source of ...
Fumio Oosawa. IV . ELECTRICAL POTENTIAL AROUND THE MACROION Let us consider a macroion in the spherical random coil conformation . Many discrete charges are distributed on the macroion as shown in Fig . 4a . Each of them is the source of ...
Page 32
... macroion and gave the electric free energy as the sum of interactions between charged groups with the counter ion ... spherical macroion in concentrated salt solutions ( 11 ) . The two phase model in the previous chapter is , in a sense ...
... macroion and gave the electric free energy as the sum of interactions between charged groups with the counter ion ... spherical macroion in concentrated salt solutions ( 11 ) . The two phase model in the previous chapter is , in a sense ...
Page 40
... spherical macroion in a spherical free volume , for comparison with the case of the rigid rod . The Poisson - Boltzmann equation is written where and Δψ = - — ( 4ñe 。/ ɛ 。) А exp ( −e 。¥ / kT ) A = d2 / dr2 + ( 2 / r ) ( d / dr ) R ...
... spherical macroion in a spherical free volume , for comparison with the case of the rigid rod . The Poisson - Boltzmann equation is written where and Δψ = - — ( 4ñe 。/ ɛ 。) А exp ( −e 。¥ / kT ) A = d2 / dr2 + ( 2 / r ) ( d / dr ) R ...
Contents
Preface | 1 |
theoretically understandable Idealized treatment based on the simplest | 5 |
Electrical Potential Around the Macroion | 9 |
Copyright | |
17 other sections not shown
Common terms and phrases
absence of salt activity coefficient activity of counter addition of salt additivity law alkali apparent charge average bound counter ions chain Chapter charge density charged groups chemical potential coefficient of counter concentration of counter concentration of free concentration of macroions copolymer counter ion condensation critical value cylindrical macroion decreases degree of dissociation degree of neutralization density Q derived dielectric constant dielectric increment electric free energy electric potential entropy equilibrium experimental extensive force fluctuation free counter ions free energy free volume hydrogen ions increase interaction ionized groups kinds of counter macromolecules monomers monovalent number of charged number of counter number of free osmotic coefficient osmotic pressure Poisson-Boltzmann equation polyacids polyacrylic acid polyelectrolytes polyvalent counter ions proportional radius random coil ratio refractive index region relation result rodlike macroions rods salt concentration salt solution shown in Fig simple salt small ions sodium ions spherical macroion total number valence