High Temperature Vapors: Science and Technology |
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Page 18
... entropy of a gaseous species can be calculated from basic molecular parameters , by statistical thermodynamics , and is therefore not reliant on experimental thermodynamics , e.g. , see Margrave ( 1967a ) . As an example , for a vapor ...
... entropy of a gaseous species can be calculated from basic molecular parameters , by statistical thermodynamics , and is therefore not reliant on experimental thermodynamics , e.g. , see Margrave ( 1967a ) . As an example , for a vapor ...
Page 71
... entropy change is also in accord with the entropy " rules " given in Chapter 3 , Section IV . For the analogous cases involving M ( OH ) 3 and M ( OH ) 4 , AS3 values of −3 and −2 cal deg1 mol - 1 , respec- tively , are similarly ...
... entropy change is also in accord with the entropy " rules " given in Chapter 3 , Section IV . For the analogous cases involving M ( OH ) 3 and M ( OH ) 4 , AS3 values of −3 and −2 cal deg1 mol - 1 , respec- tively , are similarly ...
Page 78
... entropy may be expressed in terms of a summation of entropy contributions from the individual molecular components , i.e. , Smolar = Σ ( 1 / n ) X ; S ; i where n is the number of molecules of H2O in species i , i.e. , 2 for dimer , 3 ...
... entropy may be expressed in terms of a summation of entropy contributions from the individual molecular components , i.e. , Smolar = Σ ( 1 / n ) X ; S ; i where n is the number of molecules of H2O in species i , i.e. , 2 for dimer , 3 ...
Contents
Introduction | 1 |
Chemistry of High Temperature Species in Space | 7 |
Appendix Major Literature Sources for High Temperature Chemistry | 36 |
Copyright | |
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addition alkali metal atoms basic bond dissociation energies Bulewicz burning velocity calculated Chapter Chem chemical reaction chemistry chloride combustion complex components composition concentration condensed considered corrosion determined diffusion flame discussion dissociation energies effect electron emission endothermic enthalpy entropy equilibrium constant example experimental fission fission products fluorides formation free energy fuel gases given H-atom H₂ H₂O halogen heat Hence high temperature species high temperature vapors hydroxide inhibition inhibitor interaction involves ionization ions kcal mol-¹ kinetic low pressure mass spectrometric materials metal halide metal oxide mole fraction molecular species NaCl nuclear fission observed oxide oxygen Padley partial pressure phase plasma premixed premixed flames presence production radical reactants reaction rates reaction zone reactor recent recombination reduced region relatively rocket Section solid solubility specific impulse spectroscopic stability Sugden surface Table techniques temperature thermal thermodynamic tion vapor deposition vapor pressure vapor species vapor-phase volatile