High Temperature Vapors: Science and Technology |
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Page 84
... mol - 1 . Taking into account the known entropy of sublimation for NaCl , i.e. , ~ + 32 cal deg1 mol - 1 , the ... kcal mol - 1 and , as AH + 5 kcal mol - 1 , it follows that AS1 = -23.5 cal deg1 mol - 1 which is basically in agreement ...
... mol - 1 . Taking into account the known entropy of sublimation for NaCl , i.e. , ~ + 32 cal deg1 mol - 1 , the ... kcal mol - 1 and , as AH + 5 kcal mol - 1 , it follows that AS1 = -23.5 cal deg1 mol - 1 which is basically in agreement ...
Page 86
... kcal mol - 1 . - Now it is well known that species such as NaCl and KCl are comprised of M + Cl- and , as the binding energy of Na + H2O is -23 kcal mol - 1 and of Cl- H2O is 13 kcal mol - 1 , one can reasonably expect Na + Cl- • H2O to ...
... kcal mol - 1 . - Now it is well known that species such as NaCl and KCl are comprised of M + Cl- and , as the binding energy of Na + H2O is -23 kcal mol - 1 and of Cl- H2O is 13 kcal mol - 1 , one can reasonably expect Na + Cl- • H2O to ...
Page 144
... ( kcal mol - 1 ) 44.5 KCl + KCI KCl + SrCl2 KCl + LaCl3 = ( KCl ) 2 , 2 = = KSrCl3 , KLaCl4 , 67 ± 17 614 KCl + ThCl = KTHCl , 49 ± 3 . ( 1 ) ( 2 ) ( 3 ) ( 4 ) Consider the application of Rules 2 , 3 , and 4 to the above reactions . From ...
... ( kcal mol - 1 ) 44.5 KCl + KCI KCl + SrCl2 KCl + LaCl3 = ( KCl ) 2 , 2 = = KSrCl3 , KLaCl4 , 67 ± 17 614 KCl + ThCl = KTHCl , 49 ± 3 . ( 1 ) ( 2 ) ( 3 ) ( 4 ) Consider the application of Rules 2 , 3 , and 4 to the above reactions . From ...
Contents
Introduction | 1 |
Chemistry of High Temperature Species in Space | 7 |
Appendix Major Literature Sources for High Temperature Chemistry | 36 |
Copyright | |
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addition alkali metal atoms basic bond dissociation energies Bulewicz burning velocity calculated Chapter Chem chemical reaction chemistry chloride combustion complex components composition concentration condensed considered corrosion determined diffusion flame discussion dissociation energies effect electron emission endothermic enthalpy entropy equilibrium constant example experimental fission fission products fluorides formation free energy fuel gases given H-atom H₂ H₂O halogen heat Hence high temperature species high temperature vapors hydroxide inhibition inhibitor interaction involves ionization ions kcal mol-¹ kinetic low pressure mass spectrometric materials metal halide metal oxide mole fraction molecular species NaCl nuclear fission observed oxide oxygen Padley partial pressure phase plasma premixed premixed flames presence production radical reactants reaction rates reaction zone reactor recent recombination reduced region relatively rocket Section solid solubility specific impulse spectroscopic stability Sugden surface Table techniques temperature thermal thermodynamic tion vapor deposition vapor pressure vapor species vapor-phase volatile