High Temperature Vapors: Science and Technology |
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Page 66
... partial pressure . If the system is at thermody- namic equilibrium , and constant temperature conditions are main- tained , then K , is constant for variable pressure . It follows that a plot of log p [ An / r • ( H2O ) q / r ] vs log p ...
... partial pressure . If the system is at thermody- namic equilibrium , and constant temperature conditions are main- tained , then K , is constant for variable pressure . It follows that a plot of log p [ An / r • ( H2O ) q / r ] vs log p ...
Page 171
... vapor pressure at a critical oxygen pressure . This observation has important implications in the possible utility of metal - fuming processes , as the control of oxygen pressure may be used to selectively extract the metal of interest ...
... vapor pressure at a critical oxygen pressure . This observation has important implications in the possible utility of metal - fuming processes , as the control of oxygen pressure may be used to selectively extract the metal of interest ...
Page 198
... PARTIAL PRESSURE ( ATM ) 6 6 T + & T 2 -8 Sb406 Cd M003 PbCl2 CdCl2 Çoqs £ ၈၁ ZnCl2 AgCl FeCl CoCl2 -3 -2 - | ii NiCl2 15 MnCl2 SnCl2 SnCl4 LOG HCI ( ATM ) Fig . 3.13 Volatilities of metal containing species as a function of HCl pressure ...
... PARTIAL PRESSURE ( ATM ) 6 6 T + & T 2 -8 Sb406 Cd M003 PbCl2 CdCl2 Çoqs £ ၈၁ ZnCl2 AgCl FeCl CoCl2 -3 -2 - | ii NiCl2 15 MnCl2 SnCl2 SnCl4 LOG HCI ( ATM ) Fig . 3.13 Volatilities of metal containing species as a function of HCl pressure ...
Contents
Appendix Major Literature Sources for High Temperature Chemistry | 36 |
Synergistic Reactions | 58 |
Appendix Some Additional Recent Literature on High Temperature GasSolid | 89 |
Copyright | |
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addition apparent application atmosphere atoms basic calculated Chapter Chem chemical chemistry chloride combustion complex components composition concentration considered constant containing corrosion dependence deposition determined diffusion discussion dissociation effect electron elements emission energy equilibrium et al evidence example experimental factor flame formation fuel gases given greater H-atom H₂O halide halogen heat Hence high temperature hydroxide important increase indicated inhibition interaction interest involving ions kcal mol-¹ kinetic known lead less limited mass materials mechanism metal molecular observed obtained occur oxide partial particularly phase Phys plasma possible practical presence present pressure problems production radical reaction reaction zone reactor recent reduced region relatively rocket shown similar solid species stability studies suggested surface Table techniques thermal thermodynamic tion transport usually values vapor vapor-phase various volatile York