High temperature vapors: science and technology |
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Page 173
In particular, the use of AlCL com- plexing (see Section IV) has allowed the
volatilization of rare earth and transuranium elements for chromatographic
separations at the relatively low temperatures of 200-250 °C (Zvarova and Zvara,
1969, ...
In particular, the use of AlCL com- plexing (see Section IV) has allowed the
volatilization of rare earth and transuranium elements for chromatographic
separations at the relatively low temperatures of 200-250 °C (Zvarova and Zvara,
1969, ...
Page 174
science and technology John W. Hastie. product. For the similar case of Zr
extraction, the relatively involatile ZrCl4 is purified by sublimation. A method for
the separation of zirconium and hafnium chlorides, which have very similar
volatilities, ...
science and technology John W. Hastie. product. For the similar case of Zr
extraction, the relatively involatile ZrCl4 is purified by sublimation. A method for
the separation of zirconium and hafnium chlorides, which have very similar
volatilities, ...
Page 224
Silica is much more subject to sulfur corrosion than alumina owing to the
relatively high stability of the SiS species, i.e., Do SiS = 149 whereas Do AlS = 88
kcal mol-1 — see the review of Hauge and Margrave (1972). On the other hand, ...
Silica is much more subject to sulfur corrosion than alumina owing to the
relatively high stability of the SiS species, i.e., Do SiS = 149 whereas Do AlS = 88
kcal mol-1 — see the review of Hauge and Margrave (1972). On the other hand, ...
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Contents
Introduction | 1 |
Appendix Major Literature Sources for High Temperature Chemistry | 36 |
GraphiteGas Reactions | 59 |
Copyright | |
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absorption addition alkali metal atoms ature basic bond dissociation energies bond energies burning velocity calculated Chapter chemical reaction chemistry chloride coefficient combustion complex components composition condensed considered corrosion determined diffusion flame discussion dissociation energies effect electron emission endothermic enthalpy entropy equilibrium constant example experimental fission fission products flame inhibition fluorides formation free energy fuel gases given H-atom halogen heat Hence high temperature species high temperature vapors hydroxide indicated inhibitor interaction involves ionization ions kcal mol-1 kinetic mass spectrometric materials metal halide metal oxide mole mole fraction molecular species NaCl nuclear fission observed oxide oxygen Padley partial pressure phase plasma premixed premixed flames presence production radical reactants reaction rates reaction zone reactor recent recombination reduced region relatively rocket Section solid solubility specific impulse stability surface Table techniques thermal thermodynamic tion vapor deposition vapor pressure vapor species vapor-phase volatile