High Temperature Vapors: Science and Technology |
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Page 62
... similar . This follows from the similar reaction entropies and enthalpies that may be estimated for reactions ( 4 ) and ( 5 ) . In both cases the reaction involves the conversion of a metal - oxygen double bond to two metal- hydroxyl ...
... similar . This follows from the similar reaction entropies and enthalpies that may be estimated for reactions ( 4 ) and ( 5 ) . In both cases the reaction involves the conversion of a metal - oxygen double bond to two metal- hydroxyl ...
Page 77
... similar to that determined by the ab initio calculations and estimated vibration frequencies is -31 ± 2 cal deg1 mol - 1 . These values are consistent with the average entropy change of -30 ± 4 cal deg - 1 mol - 1 found for a large ...
... similar to that determined by the ab initio calculations and estimated vibration frequencies is -31 ± 2 cal deg1 mol - 1 . These values are consistent with the average entropy change of -30 ± 4 cal deg - 1 mol - 1 found for a large ...
Page 128
... similar to the heat Al2Cle = 2AICI3 , and this is suggestive of similar bonding in both complexes - namely , halogen bridging . 2. ZrCl4 POCI3 Vapor density measurements indicate the formation of a vapor - phase complex species ZrCl1 ...
... similar to the heat Al2Cle = 2AICI3 , and this is suggestive of similar bonding in both complexes - namely , halogen bridging . 2. ZrCl4 POCI3 Vapor density measurements indicate the formation of a vapor - phase complex species ZrCl1 ...
Contents
Appendix Major Literature Sources for High Temperature Chemistry | 36 |
Synergistic Reactions | 58 |
Appendix Some Additional Recent Literature on High Temperature GasSolid | 89 |
Copyright | |
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addition apparent application atmosphere atoms basic calculated Chapter Chem chemical chemistry chloride combustion complex components composition concentration considered constant containing corrosion dependence deposition determined diffusion discussion dissociation effect electron elements emission energy equilibrium et al evidence example experimental factor flame formation fuel gases given greater H-atom H₂O halide halogen heat Hence high temperature hydroxide important increase indicated inhibition interaction interest involving ions kcal mol-¹ kinetic known lead less limited mass materials mechanism metal molecular observed obtained occur oxide partial particularly phase Phys plasma possible practical presence present pressure problems production radical reaction reaction zone reactor recent reduced region relatively rocket shown similar solid species stability studies suggested surface Table techniques thermal thermodynamic tion transport usually values vapor vapor-phase various volatile York