High Temperature Vapors: Science and Technology |
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Page 77
... values , i.e. , less than about 10 kcal mol - 1 , to have AS values at the high end of this range . The most probable values of AS and AH for water dimerization are considered to be - - and ASdim = -32 ± 2 cal deg1 mol - 1 = -7.42 kcal ...
... values , i.e. , less than about 10 kcal mol - 1 , to have AS values at the high end of this range . The most probable values of AS and AH for water dimerization are considered to be - - and ASdim = -32 ± 2 cal deg1 mol - 1 = -7.42 kcal ...
Page 144
... values do not follow the same trend as the experimental data . Consider now the enhanced stabilization , as derived ... values of 20 and 15 kcal mol - 1 are estimated , respectively . The total reaction enthalpies are then determined to ...
... values do not follow the same trend as the experimental data . Consider now the enhanced stabilization , as derived ... values of 20 and 15 kcal mol - 1 are estimated , respectively . The total reaction enthalpies are then determined to ...
Page 328
... values for elements such as Mg , Mn , Si , and Sr , which form stable oxides or hy- droxides , is thought to be due to the unusually strong dependence of 8 on flame composition , as may be thermodynamically predicted . As an example of ...
... values for elements such as Mg , Mn , Si , and Sr , which form stable oxides or hy- droxides , is thought to be due to the unusually strong dependence of 8 on flame composition , as may be thermodynamically predicted . As an example of ...
Contents
Chemistry of High Temperature Species in Space | 7 |
Appendix Major Literature Sources for High Temperature Chemistry | 36 |
Synergistic Reactions | 58 |
Copyright | |
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addition alkali metal atoms basic bond dissociation energies Bulewicz burning velocity calculated Chapter Chem chemical reaction chemistry chloride combustion complex components composition concentration condensed considered corrosion determined diffusion flames discussion dissociation energies effect electron emission endothermic enthalpy entropy equilibrium constant example experimental fission fission products fluorides formation free energy fuel gases given H-atom H₂ H₂O halogen heat Hence high temperature species high temperature vapors hydroxide inhibition inhibitor interaction involves ionization ions kcal mol-¹ kinetic low pressure mass spectrometric materials metal halide metal oxide mole fraction molecular species NaCl nuclear fission observed oxide oxygen Padley partial pressure phase plasma premixed premixed flames presence production radical reactants reaction rates reaction zone reactor recent recombination reduced region relatively rocket Section solid solubility specific impulse spectroscopic stability Sugden surface Table techniques temperature thermal thermodynamic tion vapor deposition vapor pressure vapor species vapor-phase volatile