Membrane ElectrodesMembrane Electrodes considers the significant developments in the field of sensing probes, with an emphasis on membrane electrodes. This book is organized into three parts encompassing 11 chapters. Part I is an introduction to the variety of ion-selective membrane electrodes that have been constructed and with which experiments have been conducted. This part deals first with the thermodynamic principles and other concepts underlying the description of the behavior of electrolyte solutions, followed by a discussion on the various theories of membrane potential applicable to a variety of solid and liquid membrane electrodes. Part II describes the preparation, properties, and uses of the various solid and liquid membrane electrodes. Part III presents glass membrane electrodes as a prelude to the description of other membrane systems in which glass electrodes are invariably used as the primary sensing device. This book will prove useful to students, technologists, and researchers in various fields of science and technology. |
Contents
Electrochemistry of Aqueous Electrolyte | 22 |
Theories of Membrane Electrode Potentials 50 | 50 |
Organic Ion Exchangers | 97 |
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a₁ acid Acta activity coefficients Ag₂S Aliquat 336S alkali ammonium Anal anion aqueous buffer Ca2+ cation cell Chapter Chem Chim chloride complex concentration range Cu2+ cyanide determined diffusion Eisenman electrode response electrodes selective electrolyte enzyme enzyme electrode equation equilibrium fluoride G. A. Rechnitz gel layer given in Table glass electrode glass membrane electrode glucose halide Interfering ion iodide ion activity Ion Selective Electrodes ion-selective ionic strength K+ ions K₂ Lett ligand liquid membrane electrode Mascini measured membrane electrode membrane phase membrane potential metal ions Methanol Mg2+ mixture molality mole NaCl NaClO4 Nernstian response nonactin Orion oxygen phosphate Phys polyvinyl chloride Pungor reaction reference electrode salt sample Selectivity Constants Kpot Silicone rubber silver silver sulfide slope Solid state heterogeneous solubility solvent species sulfide sulfonate surface titrations Toth urea urease valinomycin values