Interfacial Forces in Aqueous MediaThoroughly revised and reorganized, the second edition of Interfacial Forcesin Aqueous Media examines the role of polar interfacial and noncovalent interactions among biological and nonbiological macromolecules as well as biopolymers, particles, surfaces, cells, and both polar and apolar polymers. The book encompasses Lifshitz-van de |
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Page 20
... Table III - 3 agrees well with the values found by Hough and White ( 1980 , Table III - 4 ) for alkanes with a fairly high carbon number ( n ≥ 9 ) ; for the lower alkanes ( n ≥ 7 ) these authors found a slightly higher value for ...
... Table III - 3 agrees well with the values found by Hough and White ( 1980 , Table III - 4 ) for alkanes with a fairly high carbon number ( n ≥ 9 ) ; for the lower alkanes ( n ≥ 7 ) these authors found a slightly higher value for ...
Page 21
... Table III - 3 then becomes ≈1.36 Å ( van Oss et al . , Chem . Rev. , 1988 ) . However , even that value does not ... TABLE III-3 LW Table of Hamaker Constants A ii and Relation Between the Hamaker Constant / Apolar Surface Tension 21.
... Table III - 3 then becomes ≈1.36 Å ( van Oss et al . , Chem . Rev. , 1988 ) . However , even that value does not ... TABLE III-3 LW Table of Hamaker Constants A ii and Relation Between the Hamaker Constant / Apolar Surface Tension 21.
Page 22
Carel J. van Oss. TABLE III-3 LW Table of Hamaker Constants A ii and γ i Values (at 20°C) for Various Liquids, Showing the Minimum Equilibrium Distance o from eq. [III-1] LW Hamaker constant Temperature (°C) (× 1013 ergs; γ i (ergs/cm2) ...
Carel J. van Oss. TABLE III-3 LW Table of Hamaker Constants A ii and γ i Values (at 20°C) for Various Liquids, Showing the Minimum Equilibrium Distance o from eq. [III-1] LW Hamaker constant Temperature (°C) (× 1013 ergs; γ i (ergs/cm2) ...
Page 23
Carel J. van Oss. TABLE III - 4 LW Table of Hamaker Constants A12 and Apolar Interfacial Free Energy AG12 at 20 ° C , Between Alkanes ( 1 ) and Water ( 2 ) , Giving the Practical Equilibrium Distance A calc.d Alkane ( carbon number ) ...
Carel J. van Oss. TABLE III - 4 LW Table of Hamaker Constants A12 and Apolar Interfacial Free Energy AG12 at 20 ° C , Between Alkanes ( 1 ) and Water ( 2 ) , Giving the Practical Equilibrium Distance A calc.d Alkane ( carbon number ) ...
Page 24
... Table XVI ; Hough and White , 1980 , Table 5 ) . However , the data of Hough and White ( 1980 , Table 4 ) on hydrocarbon - water systems ( of which the y ! and the y values can be established with greater precision than those for ...
... Table XVI ; Hough and White , 1980 , Table 5 ) . However , the data of Hough and White ( 1980 , Table 4 ) on hydrocarbon - water systems ( of which the y ! and the y values can be established with greater precision than those for ...
Contents
1 | |
9 | |
19 | |
25 | |
5 Electrical Double Layer Interactions | 51 |
6 Brownian Movement ForcesOsmotic Interactions of Polymers | 71 |
7 Rate of Decay with Distance | 79 |
8 Lifshitzvan der Waals and Lewis AcidBase Properties of Liquid WaterPhysical and PhysicoChemical Effects | 93 |
16 Direct Measurement Methods Treating the Force Balance in Particular | 203 |
17 Surface Tension Components and Parameters of Liquids and Solids | 213 |
Hydrophobic Interactions | 227 |
Hydrophilic InteractionsOsmotic Pressures of PEO Solutions | 243 |
20 The Primary and Secondary Interactions | 263 |
21 Phase Separation in Polymer Solutions Coacervation and Complex Coacervation | 275 |
22 Solubility of Polymers and Other Solutes | 297 |
23 Cell and Particle Stability | 319 |
9 Role of Water in Hydrophobic Attraction | 101 |
10 Role of Water in Hydrophilic Repulsion | 109 |
11 The WaterAir Interface | 117 |
12 Contact Angleand Surface Tension Determination and Preparation of Solid Surfaces | 131 |
13 Interfacial Tension DeterminationInfluence of Macroscopic and MicroscopicScale Interactions | 157 |
14 Different Approaches for Interpreting Contact Angles and Determining the Surface Tension and Surface Tension Components of Solids | 165 |
15 Electrokinetic Methods | 179 |
24 Adsorption and Adhesion in Aqueous Media Including LigandReceptor Interactions | 345 |
25 Kinetics and Energetics of Protein Adsorption onto Metal Oxide Surfaces | 385 |
List of Symbols Used | 399 |
References | 407 |
Index | 431 |
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Common terms and phrases
adhesion adsorbed adsorption AGAB AGiwi AGLW antibodies approach aqueous media aqueous solution biopolymers C-potential cells Chapter XIX Chem coacervation Colloid Colloid Interface Sci complex coacervation compounds concentration contact angle contact angle measurements decay decrease Derjaguin determined dextran dissolved distance Docoslis electron-donor electrophoresis electrophoretic mobility electrostatic energy of cohesion energy of interaction epitope equation erythrocytes flocculation formamide free energy Giese glycerol human serum albumin hydration hydrophilic hydrophobic attraction immersed in water interaction energy interfacial tension ionic strength isoelectric Israelachvili Lewis acid-base low-energy LW LW LW macromolecules macroscopic-scale materials miscibility mJ/m² moieties molecular weight molecules or particles monopolar Neumann obtained occur Overbeek parameter paratope phase separation polar liquids polymer polymer molecules protein solid surface solubility solvent specific stability surface tension surface tension components surfactant Table temperature water molecules water-air interface whilst zero