Interfacial Forces in Aqueous MediaThoroughly revised and reorganized, the second edition of Interfacial Forcesin Aqueous Media examines the role of polar interfacial and noncovalent interactions among biological and nonbiological macromolecules as well as biopolymers, particles, surfaces, cells, and both polar and apolar polymers. The book encompasses Lifshitz-van de |
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Page xi
... Electron-Acceptor and Electron-Donor Parameters of γ .........31 Monopolar Surfaces and Substances .......................................................................33 Different Modes of Interaction ...
... Electron-Acceptor and Electron-Donor Parameters of γ .........31 Monopolar Surfaces and Substances .......................................................................33 Different Modes of Interaction ...
Page 1
... electron - donor - electron - acceptor interactions among the non - covalent interactions , even though some authors ( see , e.g. , Drago et al . , 1971 ) classify these interactions as at least partly covalent . The non - covalent ...
... electron - donor - electron - acceptor interactions among the non - covalent interactions , even though some authors ( see , e.g. , Drago et al . , 1971 ) classify these interactions as at least partly covalent . The non - covalent ...
Page 3
... electron-donor–electron- acceptor interactions frequently are not “dipole” interactions sensu stricto (Fowkes, 1983; van Oss et al., Advan. Coll. Interf. Sci., 1987), their strong electrostatic component (Kollman, 1977) and especially ...
... electron-donor–electron- acceptor interactions frequently are not “dipole” interactions sensu stricto (Fowkes, 1983; van Oss et al., Advan. Coll. Interf. Sci., 1987), their strong electrostatic component (Kollman, 1977) and especially ...
Page 25
... donors and hydrogen- acceptors ( or between Brønsted acids and Brønsted bases ) . It is , however , preferable to extend the concept of polar interactions more widely , and to define them to comprise all electron - acceptor - electron - ...
... donors and hydrogen- acceptors ( or between Brønsted acids and Brønsted bases ) . It is , however , preferable to extend the concept of polar interactions more widely , and to define them to comprise all electron - acceptor - electron - ...
Page 26
... electron - donor interactions are essentially asymmetrical ( van Oss et al . , Advan . Colloid Interface Sci . , 1987 ) in the sense that of a given polar substance i the electron - acceptor and the electrondonor parameters are usually ...
... electron - donor interactions are essentially asymmetrical ( van Oss et al . , Advan . Colloid Interface Sci . , 1987 ) in the sense that of a given polar substance i the electron - acceptor and the electrondonor parameters are usually ...
Contents
1 | |
9 | |
19 | |
25 | |
5 Electrical Double Layer Interactions | 51 |
6 Brownian Movement ForcesOsmotic Interactions of Polymers | 71 |
7 Rate of Decay with Distance | 79 |
8 Lifshitzvan der Waals and Lewis AcidBase Properties of Liquid WaterPhysical and PhysicoChemical Effects | 93 |
16 Direct Measurement Methods Treating the Force Balance in Particular | 203 |
17 Surface Tension Components and Parameters of Liquids and Solids | 213 |
Hydrophobic Interactions | 227 |
Hydrophilic InteractionsOsmotic Pressures of PEO Solutions | 243 |
20 The Primary and Secondary Interactions | 263 |
21 Phase Separation in Polymer Solutions Coacervation and Complex Coacervation | 275 |
22 Solubility of Polymers and Other Solutes | 297 |
23 Cell and Particle Stability | 319 |
9 Role of Water in Hydrophobic Attraction | 101 |
10 Role of Water in Hydrophilic Repulsion | 109 |
11 The WaterAir Interface | 117 |
12 Contact Angleand Surface Tension Determination and Preparation of Solid Surfaces | 131 |
13 Interfacial Tension DeterminationInfluence of Macroscopic and MicroscopicScale Interactions | 157 |
14 Different Approaches for Interpreting Contact Angles and Determining the Surface Tension and Surface Tension Components of Solids | 165 |
15 Electrokinetic Methods | 179 |
24 Adsorption and Adhesion in Aqueous Media Including LigandReceptor Interactions | 345 |
25 Kinetics and Energetics of Protein Adsorption onto Metal Oxide Surfaces | 385 |
List of Symbols Used | 399 |
References | 407 |
Index | 431 |
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Common terms and phrases
adhesion adsorbed adsorption AGAB AGiwi AGLW antibodies approach aqueous media aqueous solution biopolymers C-potential cells Chapter XIX Chem coacervation Colloid Colloid Interface Sci complex coacervation compounds concentration contact angle contact angle measurements decay decrease Derjaguin determined dextran dissolved distance Docoslis electron-donor electrophoresis electrophoretic mobility electrostatic energy of cohesion energy of interaction epitope equation erythrocytes flocculation formamide free energy Giese glycerol human serum albumin hydration hydrophilic hydrophobic attraction immersed in water interaction energy interfacial tension ionic strength isoelectric Israelachvili Lewis acid-base low-energy LW LW LW macromolecules macroscopic-scale materials miscibility mJ/m² moieties molecular weight molecules or particles monopolar Neumann obtained occur Overbeek parameter paratope phase separation polar liquids polymer polymer molecules protein solid surface solubility solvent specific stability surface tension surface tension components surfactant Table temperature water molecules water-air interface whilst zero