Interfacial Forces in Aqueous MediaThoroughly revised and reorganized, the second edition of Interfacial Forcesin Aqueous Media examines the role of polar interfacial and noncovalent interactions among biological and nonbiological macromolecules as well as biopolymers, particles, surfaces, cells, and both polar and apolar polymers. The book encompasses Lifshitz-van de |
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Page v
... water ( w ) , i.e. , Yiw , or in the closely related interfacial free energy of interaction between molecules , particles or surfaces ( i ) , immersed in water ( w ) : AG ; w ; ( where AGiwi = -2Yiw ) . Yiw iwi To explain these changes ...
... water ( w ) , i.e. , Yiw , or in the closely related interfacial free energy of interaction between molecules , particles or surfaces ( i ) , immersed in water ( w ) : AG ; w ; ( where AGiwi = -2Yiw ) . Yiw iwi To explain these changes ...
Page xvi
... Water ......................206 Interfacial Repulsion Effects (Hydration Repulsion) in Water ... Immersed in Water .......227 Enthalpy and Entropy of Hydrophobic Interactions ..............................................229 Apolar (LW) ...
... Water ......................206 Interfacial Repulsion Effects (Hydration Repulsion) in Water ... Immersed in Water .......227 Enthalpy and Entropy of Hydrophobic Interactions ..............................................229 Apolar (LW) ...
Page xvii
... Between Two Different Organic Compounds Immersed in Water ........... 238 Occurrence of Attractive Interfacial (“Hydrophobic”) Interactions Between Two Dissimilar Sites .......................................................................
... Between Two Different Organic Compounds Immersed in Water ........... 238 Occurrence of Attractive Interfacial (“Hydrophobic”) Interactions Between Two Dissimilar Sites .......................................................................
Page xix
... Water ................336 Cell and Particle Stability in the Absence and in the Presence of Polymers .........339 ... Immersed in Water .......................345 Macroscopic and Microscopic-Scale Interactions ...
... Water ................336 Cell and Particle Stability in the Absence and in the Presence of Polymers .........339 ... Immersed in Water .......................345 Macroscopic and Microscopic-Scale Interactions ...
Page 3
... immersed in a polar liquid such as water, polymers or particles with the same sign of charge will repel each other. In most such systems the resulting energy of intermolecular or interparticulate repulsion may well be too strong, in ...
... immersed in a polar liquid such as water, polymers or particles with the same sign of charge will repel each other. In most such systems the resulting energy of intermolecular or interparticulate repulsion may well be too strong, in ...
Contents
1 | |
9 | |
19 | |
25 | |
5 Electrical Double Layer Interactions | 51 |
6 Brownian Movement ForcesOsmotic Interactions of Polymers | 71 |
7 Rate of Decay with Distance | 79 |
8 Lifshitzvan der Waals and Lewis AcidBase Properties of Liquid WaterPhysical and PhysicoChemical Effects | 93 |
16 Direct Measurement Methods Treating the Force Balance in Particular | 203 |
17 Surface Tension Components and Parameters of Liquids and Solids | 213 |
Hydrophobic Interactions | 227 |
Hydrophilic InteractionsOsmotic Pressures of PEO Solutions | 243 |
20 The Primary and Secondary Interactions | 263 |
21 Phase Separation in Polymer Solutions Coacervation and Complex Coacervation | 275 |
22 Solubility of Polymers and Other Solutes | 297 |
23 Cell and Particle Stability | 319 |
9 Role of Water in Hydrophobic Attraction | 101 |
10 Role of Water in Hydrophilic Repulsion | 109 |
11 The WaterAir Interface | 117 |
12 Contact Angleand Surface Tension Determination and Preparation of Solid Surfaces | 131 |
13 Interfacial Tension DeterminationInfluence of Macroscopic and MicroscopicScale Interactions | 157 |
14 Different Approaches for Interpreting Contact Angles and Determining the Surface Tension and Surface Tension Components of Solids | 165 |
15 Electrokinetic Methods | 179 |
24 Adsorption and Adhesion in Aqueous Media Including LigandReceptor Interactions | 345 |
25 Kinetics and Energetics of Protein Adsorption onto Metal Oxide Surfaces | 385 |
List of Symbols Used | 399 |
References | 407 |
Index | 431 |
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Common terms and phrases
adhesion adsorbed adsorption AGAB AGiwi AGLW antibodies approach aqueous media aqueous solution biopolymers C-potential cells Chapter XIX Chem coacervation Colloid Colloid Interface Sci complex coacervation compounds concentration contact angle contact angle measurements decay decrease Derjaguin determined dextran dissolved distance Docoslis electron-donor electrophoresis electrophoretic mobility electrostatic energy of cohesion energy of interaction epitope equation erythrocytes flocculation formamide free energy Giese glycerol human serum albumin hydration hydrophilic hydrophobic attraction immersed in water interaction energy interfacial tension ionic strength isoelectric Israelachvili Lewis acid-base low-energy LW LW LW macromolecules macroscopic-scale materials miscibility mJ/m² moieties molecular weight molecules or particles monopolar Neumann obtained occur Overbeek parameter paratope phase separation polar liquids polymer polymer molecules protein solid surface solubility solvent specific stability surface tension surface tension components surfactant Table temperature water molecules water-air interface whilst zero