Interfacial Forces in Aqueous MediaThoroughly revised and reorganized, the second edition of Interfacial Forcesin Aqueous Media examines the role of polar interfacial and noncovalent interactions among biological and nonbiological macromolecules as well as biopolymers, particles, surfaces, cells, and both polar and apolar polymers. The book encompasses Lifshitz-van de |
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Page xiii
... .................93 Effect of Temperature on the γ-Components of Water ............................................94 The Surface Properties of Ice at 0°C Cluster Formation in Liquid Water .................................
... .................93 Effect of Temperature on the γ-Components of Water ............................................94 The Surface Properties of Ice at 0°C Cluster Formation in Liquid Water .................................
Page xiv
... .................149 Influence of Temperature on the Properties of Water as a Contact Angle Liquid ........ 149 Influence of the pH of Water as a Contact Angle Liquid on the Surface Properties of Electrically Charged Solid Surfaces ...
... .................149 Influence of Temperature on the Properties of Water as a Contact Angle Liquid ........ 149 Influence of the pH of Water as a Contact Angle Liquid on the Surface Properties of Electrically Charged Solid Surfaces ...
Page 4
... temperatures higher than 0°K. All particles (or molecules), big or small, are endowed with a Brownian (BR) free energy of +11⁄2 kT, when they have three degrees of freedom. Thus especially for the smaller colloidal-sized particles and ...
... temperatures higher than 0°K. All particles (or molecules), big or small, are endowed with a Brownian (BR) free energy of +11⁄2 kT, when they have three degrees of freedom. Thus especially for the smaller colloidal-sized particles and ...
Page 9
... temperature ) occurred , apparently caused by an interatomic or intermolecular attraction between neutral gas atoms or molecules ( van der Waals , 1873 , 1899 ) . These non - covalent , non - electrostatic inter - molecualr interactions ...
... temperature ) occurred , apparently caused by an interatomic or intermolecular attraction between neutral gas atoms or molecules ( van der Waals , 1873 , 1899 ) . These non - covalent , non - electrostatic inter - molecualr interactions ...
Page 13
... temperature , c the velocity of light in vacuo , and P an integration parameter . A1 , △ 2 and ∞ are given as follows : Δι ε1 ( in ) - εз ( in ) = ε1 ( in ) + ε3 ( io ) [ II - 19 ] Δ2 : = ε2 ( i ) -3 ( in ) Ɛ2 ( in ) + Ɛ3 ( in ) Wn ...
... temperature , c the velocity of light in vacuo , and P an integration parameter . A1 , △ 2 and ∞ are given as follows : Δι ε1 ( in ) - εз ( in ) = ε1 ( in ) + ε3 ( io ) [ II - 19 ] Δ2 : = ε2 ( i ) -3 ( in ) Ɛ2 ( in ) + Ɛ3 ( in ) Wn ...
Contents
1 | |
9 | |
19 | |
25 | |
5 Electrical Double Layer Interactions | 51 |
6 Brownian Movement ForcesOsmotic Interactions of Polymers | 71 |
7 Rate of Decay with Distance | 79 |
8 Lifshitzvan der Waals and Lewis AcidBase Properties of Liquid WaterPhysical and PhysicoChemical Effects | 93 |
16 Direct Measurement Methods Treating the Force Balance in Particular | 203 |
17 Surface Tension Components and Parameters of Liquids and Solids | 213 |
Hydrophobic Interactions | 227 |
Hydrophilic InteractionsOsmotic Pressures of PEO Solutions | 243 |
20 The Primary and Secondary Interactions | 263 |
21 Phase Separation in Polymer Solutions Coacervation and Complex Coacervation | 275 |
22 Solubility of Polymers and Other Solutes | 297 |
23 Cell and Particle Stability | 319 |
9 Role of Water in Hydrophobic Attraction | 101 |
10 Role of Water in Hydrophilic Repulsion | 109 |
11 The WaterAir Interface | 117 |
12 Contact Angleand Surface Tension Determination and Preparation of Solid Surfaces | 131 |
13 Interfacial Tension DeterminationInfluence of Macroscopic and MicroscopicScale Interactions | 157 |
14 Different Approaches for Interpreting Contact Angles and Determining the Surface Tension and Surface Tension Components of Solids | 165 |
15 Electrokinetic Methods | 179 |
24 Adsorption and Adhesion in Aqueous Media Including LigandReceptor Interactions | 345 |
25 Kinetics and Energetics of Protein Adsorption onto Metal Oxide Surfaces | 385 |
List of Symbols Used | 399 |
References | 407 |
Index | 431 |
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Common terms and phrases
adhesion adsorbed adsorption AGAB AGiwi AGLW antibodies approach aqueous media aqueous solution biopolymers C-potential cells Chapter XIX Chem coacervation Colloid Colloid Interface Sci complex coacervation compounds concentration contact angle contact angle measurements decay decrease Derjaguin determined dextran dissolved distance Docoslis electron-donor electrophoresis electrophoretic mobility electrostatic energy of cohesion energy of interaction epitope equation erythrocytes flocculation formamide free energy Giese glycerol human serum albumin hydration hydrophilic hydrophobic attraction immersed in water interaction energy interfacial tension ionic strength isoelectric Israelachvili Lewis acid-base low-energy LW LW LW macromolecules macroscopic-scale materials miscibility mJ/m² moieties molecular weight molecules or particles monopolar Neumann obtained occur Overbeek parameter paratope phase separation polar liquids polymer polymer molecules protein solid surface solubility solvent specific stability surface tension surface tension components surfactant Table temperature water molecules water-air interface whilst zero