Foundations of Colloid Science, Volume 2While Volume I stands as an essentially complete advanced textbook of colloidal science, Volume II extends the material to include important new areas, and develops some of the topics in much greater depth. An introductory chapter on the theory of liquids describes the concept of correlation functions and the use of Fourier transforms to analyse the scattering of light and neutrons by colloidal systems. Absorption is given detailed coverage and a chapter on electrokinetics introduces a new approach to time-dependent processes in the double layer. The principles of double layer theory are also used to review the behavior of thin films and emulsions. A final chapter on the rheology of colloidal suspensions calls on many of the concepts developed earlier to bring some cohesion to this important and rapidly developing field. |
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Page 742
Of the various attempts to rationalise this behaviour we will examine , in detail ,
only the most highly developed . The site - dissociation - site - binding model
which grew out of the early analyses of Yates et al . ( 1974 ) and Bowden et al .
Of the various attempts to rationalise this behaviour we will examine , in detail ,
only the most highly developed . The site - dissociation - site - binding model
which grew out of the early analyses of Yates et al . ( 1974 ) and Bowden et al .
Page 747
The Bowden model postulates that a neutral site should be defined by the group
OH - M – OH , so that only one charged site ( either + or - ) can develop for every
two surface oxygens . Their N , value is , therefore , perhaps half of that used by ...
The Bowden model postulates that a neutral site should be defined by the group
OH - M – OH , so that only one charged site ( either + or - ) can develop for every
two surface oxygens . Their N , value is , therefore , perhaps half of that used by ...
Page 878
2 ) and double layers will be expected to develop in the region 0 < x < b . These
double layers are assumed to be part of the phase ... 11 ) in accordance with the
ideas developed in Section 12 . 3 . Again d will be of the order of a few molecular
...
2 ) and double layers will be expected to develop in the region 0 < x < b . These
double layers are assumed to be part of the phase ... 11 ) in accordance with the
ideas developed in Section 12 . 3 . Again d will be of the order of a few molecular
...
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Contents
Contents of Volume I | 675 |
ADSORPTION FROM SOLUTION | 709 |
THE ELECTROKINETIC EFFECTS 786 13 THE ELECTROKINETIC EFFECTS | 786 |
Copyright | |
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adsorbed adsorption applied approach approximation assumed average becomes behaviour bulk calculated Chapter charge Chem Colloid interface Sci colloidal component concentration constant correlation corresponding density depends described determined developed direction discussed dispersion distance double layer droplets effect electrical electrokinetic electrolyte emulsion energy equation equilibrium estimate et al example Exercise experimental expression factor field film flow fluid force fraction function given gives groups important increases interaction interface involved ions limit liquid material measured microemulsion molecules Note observed obtained occur pair parameters particles phase positive possible potential present pressure problem procedure radius range reduces referred region result scattering Section separation shear rate shown solution specific spheres stability stress structure surface surface charge surface tension suspension theory thin usually values viscosity volume zero