## Foundations of colloid science, Volume 2While Volume I stands as an essentially complete advanced textbook of colloidal science, Volume II extends the material to include important new areas, and develops some of the topics in much greater depth. An introductory chapter on the theory of liquids describes the concept of correlation functions and the use of Fourier transforms to analyse the scattering of light and neutrons by colloidal systems. Absorption is given detailed coverage and a chapter on electrokinetics introduces a new approach to time-dependent processes in the double layer. The principles of double layer theory are also used to review the behavior of thin films and emulsions. A final chapter on the rheology of colloidal suspensions calls on many of the concepts developed earlier to bring some cohesion to this important and rapidly developing field. |

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Page 680

Therefore (pgfa, r2)dV2) is the conditional probability of observing a molecule in

the volume element dV2 located at r2,

. In a bulk liquid the pair distribution function can only be a function of the ...

Therefore (pgfa, r2)dV2) is the conditional probability of observing a molecule in

the volume element dV2 located at r2,

**given**that a molecule is already in dV, at rx. In a bulk liquid the pair distribution function can only be a function of the ...

Page 681

any

molecules also forces the existence of a shell of second nearest neighbour

molecules. However, as one goes further from the central molecule, correlations

...

any

**given**molecule. By a similar argument, this shell of first nearest neighbourmolecules also forces the existence of a shell of second nearest neighbour

molecules. However, as one goes further from the central molecule, correlations

...

Page 863

probability of a

separated by a

takes us well beyond the scope of this book, and the interested reader is referred

to Rose ...

probability of a

**given**relative particle orientation when the particles areseparated by a

**given**distance. The general methodology of such computationstakes us well beyond the scope of this book, and the interested reader is referred

to Rose ...

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### Contents

INTRODUCTION TO STATISTICAL MECHANICS | 675 |

ADSORPTION FROM SOLUTION | 709 |

THE ELECTROKINETIC EFFECTS | 786 |

Copyright | |

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### Common terms and phrases

adsorbed adsorption approximation assumed average behaviour bulk calculated Chapter Chem co-surfactant coagulation coalescence Colloid interface Sci colloidal dispersion colloidal particles compare with eqn component constant correlation function corresponding counterions diameter diffuse dilute double layer droplets effect electrical electrokinetic electrolyte electrostatic emulsion equilibrium Establish eqn estimate Exercise experimental Faraday ferrofluid field film flow fluid force free energy given hard sphere head group Hunter hydrophilic increases interaction ion density latex linear liquid magnetic measured micelles microemulsion molecules neutron Newtonian fluid non-ionic surfactant Note obtained occur Ottewill Overbeek pair parameters phase Phys plane polymer potential potential determining ions pressure procedure pseudoplastic radius region repulsion result scattering shear rate shear stress shown in Fig solution specific adsorption spherical stability surface charge surfactant suspension temperature thermodynamic thin thixotropic values velocity visco-elastic viscometer viscosity volume fraction Waals zero