## Foundations of colloid science, Volume 2While Volume I stands as an essentially complete advanced textbook of colloidal science, Volume II extends the material to include important new areas, and develops some of the topics in much greater depth. An introductory chapter on the theory of liquids describes the concept of correlation functions and the use of Fourier transforms to analyse the scattering of light and neutrons by colloidal systems. Absorption is given detailed coverage and a chapter on electrokinetics introduces a new approach to time-dependent processes in the double layer. The principles of double layer theory are also used to review the behavior of thin films and emulsions. A final chapter on the rheology of colloidal suspensions calls on many of the concepts developed earlier to bring some cohesion to this important and rapidly developing field. |

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Page 744

Davis et al. assume that at any pH (not too close to the p.z.c.) only one of the

possible sites is present and the

single site model. This assumption is, however, strictly correct only when the acid

...

Davis et al. assume that at any pH (not too close to the p.z.c.) only one of the

possible sites is present and the

**procedure**is then essentially the same as for asingle site model. This assumption is, however, strictly correct only when the acid

...

Page 753

J Combining eqns (12.5.5), (12.5.6), and (12.5.7) then gives (Exercise 12.5.2): In /

C = f lncA:d£Soc- (12.5.9) (This

measured values of cK as a function of Esoc (i.e. of the surface charge)).

J Combining eqns (12.5.5), (12.5.6), and (12.5.7) then gives (Exercise 12.5.2): In /

C = f lncA:d£Soc- (12.5.9) (This

**procedure**assumes, of course, that one hasmeasured values of cK as a function of Esoc (i.e. of the surface charge)).

Page 818

As an illustration of this

dxp around a sphere in an otherwise uniform electric field E. Let r denote the

vector from the centre of the sphere to an arbitrary point in the electrolyte, and let

En ...

As an illustration of this

**procedure**, consider the form of the electrical potentialdxp around a sphere in an otherwise uniform electric field E. Let r denote the

vector from the centre of the sphere to an arbitrary point in the electrolyte, and let

En ...

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### Contents

INTRODUCTION TO STATISTICAL MECHANICS | 675 |

ADSORPTION FROM SOLUTION | 709 |

THE ELECTROKINETIC EFFECTS | 786 |

Copyright | |

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### Common terms and phrases

adsorbed adsorption approximation assumed average behaviour bulk calculated Chapter Chem co-surfactant coagulation coalescence Colloid interface Sci colloidal dispersion colloidal particles compare with eqn component constant correlation function corresponding counterions diameter diffuse dilute double layer droplets effect electrical electrokinetic electrolyte electrostatic emulsion equilibrium Establish eqn estimate Exercise experimental Faraday ferrofluid field film flow fluid force free energy given hard sphere head group Hunter hydrophilic increases interaction ion density latex linear liquid magnetic measured micelles microemulsion molecules neutron Newtonian fluid non-ionic surfactant Note obtained occur Ottewill Overbeek pair parameters phase Phys plane polymer potential potential determining ions pressure procedure pseudoplastic radius region repulsion result scattering shear rate shear stress shown in Fig solution specific adsorption spherical stability surface charge surfactant suspension temperature thermodynamic thin thixotropic values velocity visco-elastic viscometer viscosity volume fraction Waals zero