Foundations of colloid science, Volume 2While Volume I stands as an essentially complete advanced textbook of colloidal science, Volume II extends the material to include important new areas, and develops some of the topics in much greater depth. An introductory chapter on the theory of liquids describes the concept of correlation functions and the use of Fourier transforms to analyse the scattering of light and neutrons by colloidal systems. Absorption is given detailed coverage and a chapter on electrokinetics introduces a new approach to time-dependent processes in the double layer. The principles of double layer theory are also used to review the behavior of thin films and emulsions. A final chapter on the rheology of colloidal suspensions calls on many of the concepts developed earlier to bring some cohesion to this important and rapidly developing field. |
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Page 810
In the double layer on the other hand, the viscous term ^(SPv/dx2) is of order t\
Vk2. The ratio of the pressure term to the viscous term is then of order l/(*ra)2 so,
by comparison, Vs/?a is negligible. On integrating eqn (13.6.8) twice with respect
to ...
In the double layer on the other hand, the viscous term ^(SPv/dx2) is of order t\
Vk2. The ratio of the pressure term to the viscous term is then of order l/(*ra)2 so,
by comparison, Vs/?a is negligible. On integrating eqn (13.6.8) twice with respect
to ...
Page 816
As the £ potential increases, the counterion density increases exponentially, and
one might expect that if the neighbouring square-bracketed term remained fixed,
the velocity would increase in a similar fashion. The increase in the velocity is ...
As the £ potential increases, the counterion density increases exponentially, and
one might expect that if the neighbouring square-bracketed term remained fixed,
the velocity would increase in a similar fashion. The increase in the velocity is ...
Page 958
Equation (16.5.5) still holds, and the problem is to make adequate calculations of
the entropy term (which is now much more important) and to estimate the
interfacial tension Yi = Yn- Overbeek (1978a) breaks the free energy change up
into a ...
Equation (16.5.5) still holds, and the problem is to make adequate calculations of
the entropy term (which is now much more important) and to estimate the
interfacial tension Yi = Yn- Overbeek (1978a) breaks the free energy change up
into a ...
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Contents
INTRODUCTION TO STATISTICAL MECHANICS | 675 |
ADSORPTION FROM SOLUTION | 709 |
THE ELECTROKINETIC EFFECTS | 786 |
Copyright | |
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Common terms and phrases
adsorbed adsorption approximation assumed average behaviour bulk calculated Chapter Chem co-surfactant coagulation coalescence Colloid interface Sci colloidal dispersion colloidal particles compare with eqn component constant correlation function corresponding counterions diameter diffuse dilute double layer droplets effect electrical electrokinetic electrolyte electrostatic emulsion equilibrium Establish eqn estimate Exercise experimental Faraday ferrofluid field film flow fluid force free energy given hard sphere head group Hunter hydrophilic increases interaction ion density latex linear liquid magnetic measured micelles microemulsion molecules neutron Newtonian fluid non-ionic surfactant Note obtained occur Ottewill Overbeek pair parameters phase Phys plane polymer potential potential determining ions pressure procedure pseudoplastic radius region repulsion result scattering shear rate shear stress shown in Fig solution specific adsorption spherical stability surface charge surfactant suspension temperature thermodynamic thin thixotropic values velocity visco-elastic viscometer viscosity volume fraction Waals zero
Bibliographic information
| Title | Foundations of colloid science, Volume 2 Foundations of Colloid Science, Robert J. Hunter Oxford science publications |
| Author | Robert J. Hunter |
| Edition | illustrated |
| Publisher | Clarendon Press, 1989 |
| Original from | the University of California |
| Digitized | 15 Feb 2011 |
| ISBN | 0198551894, 9780198551898 |
| Length | 432 pages |
| Subjects | › › Colloids Science / Applied Sciences Science / Chemistry / General Science / Chemistry / Physical & Theoretical |
| Export Citation | BiBTeX EndNote RefMan |