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Page 122
solid nitrides in silicate melts. The mechanism of nitrogen incorporation is
believed to be condensation reactions of hydroxyl and alkoxy groups with
ammonia to produce — Si — NH2 groups and water (Brinker, 1982). Further
condensation ...
solid nitrides in silicate melts. The mechanism of nitrogen incorporation is
believed to be condensation reactions of hydroxyl and alkoxy groups with
ammonia to produce — Si — NH2 groups and water (Brinker, 1982). Further
condensation ...
Page 125
The positions of the AG° versus T lines for oxidation reactions (5) and (6) allow
one to predict the stabilities of melts made from Si3N4 or AlN and various oxides.
At a given temperature, any oxide whose AGf lies above that for Reaction (5) (i.e.,
...
The positions of the AG° versus T lines for oxidation reactions (5) and (6) allow
one to predict the stabilities of melts made from Si3N4 or AlN and various oxides.
At a given temperature, any oxide whose AGf lies above that for Reaction (5) (i.e.,
...
Page 128
For example, quenching of CaO-Si02 or MgO-Si02 melts at rates common in
ordinary glass preparation gives a crystalline product. Dissolution of 10-20-wt %
Si3N4 in either melt, followed by the same quench, produces stable oxynitride ...
For example, quenching of CaO-Si02 or MgO-Si02 melts at rates common in
ordinary glass preparation gives a crystalline product. Dissolution of 10-20-wt %
Si3N4 in either melt, followed by the same quench, produces stable oxynitride ...
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Contents
Nuclear Waste Glasses | 57 |
Oxynitride Glasses | 119 |
HeavyMetal Fluoride Glasses | 151 |
Copyright | |
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Common terms and phrases
AlF3 analysis Appl Phys Basis for Nuclear bead seal behavior Bendow borosilicate glass bulk glasses bulk modulus Ceram chemical composite sphere constant cooling corrosion crystalline crystallization curve dB/km devices dielectric differential strain Drexhage durability effects elastic electron energy equation fibers fluorohafnate fluorozirconate glasses fused silica glass formation glass transition glass transition temperature glass-clad glass-forming region heavy-metal fluoride glasses increase interface traps ions layers leaching Loehman Lucas Matecki materials measured melt metal Mitachi modulus MOSFET nitride nitrogen Non-Cryst Nuclear Waste Nuclear Waste Management observed optical optical fibers oxide glasses oxynitride glasses Poulain radiation Radioactive Waste radionuclides refractive index Rekhson result sample sandwich seal Scherer seal Eq setting temperature shown in Fig Si02 films silicon Solids solution split ring stiffness ratio stress relaxation structural relaxation studies Subsection substrate surface Table techniques thermal thickness viscoelastic viscosity vitrification Waste Management waste-glass waste-glass forms wavelength ZBLA ZBLAN ZrF4
Bibliographic information
| Title | Glass IV Treatise on Materials Science and Technology, Herbert Herman Volume 26 of Glass, Minoru Tomozawa |
| Authors | Minoru Tomozawa, R. H. Doremus |
| Editors | Minoru Tomozawa, R. H. Doremus |
| Publisher | Academic Press, 1985 |
| Original from | the University of Michigan |
| Digitized | 29 Nov 2007 |
| ISBN | 0123418267, 9780123418265 |
| Length | 333 pages |
| Subjects | › Glass Materials Materials science Technology & Engineering / General Technology & Engineering / Materials Science |
| Export Citation | BiBTeX EndNote RefMan |