Physical Principles and Techniques of Protein ChemistrySydney J. Leach Physical Principles and Techniques of Protein Chemistry Part C ... |
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Page 363
... chromophore may find itself in an asymmetric field . It is much more difficult to predict this type of structure from the optical activity of the chromophores . Some proteins also contain symmetric molecules which are not cova- lently ...
... chromophore may find itself in an asymmetric field . It is much more difficult to predict this type of structure from the optical activity of the chromophores . Some proteins also contain symmetric molecules which are not cova- lently ...
Page 490
... chromophore , another chromophore , an ion , a solvent molecule , etc. The kind of perturbation which gives rise to the one - electron mechanism . is the time - averaged static field in which the chromophore is located . [ The " dynamic ...
... chromophore , another chromophore , an ion , a solvent molecule , etc. The kind of perturbation which gives rise to the one - electron mechanism . is the time - averaged static field in which the chromophore is located . [ The " dynamic ...
Page 491
... chromophore belongs ; Schellman also demon- strated that the higher the symmetry of the chromophore , the higher the multipole ( i.e. , monopole , dipole ) term in V needed to induce optical activity . Both of these findings suggest ...
... chromophore belongs ; Schellman also demon- strated that the higher the symmetry of the chromophore , the higher the multipole ( i.e. , monopole , dipole ) term in V needed to induce optical activity . Both of these findings suggest ...
Contents
Density and Volume Change Measurements | 1 |
Osmotic Pressure | 18 |
Optical Rotatory | 22 |
Copyright | |
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a-helix absorption acid angle axial ratio B-structure band Biochem Biochemistry Biol buffer c₂ calculated CD spectra Chem chromophore coefficient Cohn complex concentration conformation constant Cotton effects creatine kinase cross-section curves denaturation determined dialyzate diffusible components dilute electron density ellipsoids ellipticity enzyme equation equilibrium exciton experimental factor function grams Guinier helical helix hemocyanin hemoglobin intensity interaction investigations kinase Kratky lysozyme macromolecule magnetic measurements membrane method mg/ml molal molecular weight molecule myoglobin negative nondiffusible observed obtained optical activity osmometers osmotic pressure paramagnetic parameter partial specific volume particles peptide Phys Pilz plot polymer polypeptides Porod primary beam procedure protein protein solution pulse radii radius of gyration residues rotational strength sample Schellman Section shape small-angle scattering solvent solvent medium spectrum sphere structure studies subunits T₁ temperature theoretical scattering curves Tinoco tion transition wavelength zero