Physical Principles and Techniques of Protein ChemistrySydney J. Leach Physical Principles and Techniques of Protein Chemistry Part C ... |
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Page 396
... positive Cotton effect centered at 198-200 nm of large rotational strength . The second ( x ) is polarized in the direction of the interchain hydrogen bonds and gives rise to a smaller positive Cotton effect centered at 194-196 nm . The ...
... positive Cotton effect centered at 198-200 nm of large rotational strength . The second ( x ) is polarized in the direction of the interchain hydrogen bonds and gives rise to a smaller positive Cotton effect centered at 194-196 nm . The ...
Page 500
... positive since the optical factor is posi- tive . Conversely the rotational strength , R. , of the short - wavelength band ( A ) is negative . ( The CD spectrum for this situation is depicted in Fig . 4 if the wavelength increases from ...
... positive since the optical factor is posi- tive . Conversely the rotational strength , R. , of the short - wavelength band ( A ) is negative . ( The CD spectrum for this situation is depicted in Fig . 4 if the wavelength increases from ...
Page 543
... positive dichroism near 280 , reveals no distinct band . A significant result here is the sharp con- formation dependence and the fact that the band near 270 nm is positive , in contrast to that of N - acetyl - L - tyrosineamide in ...
... positive dichroism near 280 , reveals no distinct band . A significant result here is the sharp con- formation dependence and the fact that the band near 270 nm is positive , in contrast to that of N - acetyl - L - tyrosineamide in ...
Contents
Density and Volume Change Measurements | 1 |
Optical Rotatory | 22 |
Osmotic Pressure | 77 |
Copyright | |
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a-helix absorption acid Amer angle B-structure Biochem Biochemistry Biol Blout c₂ calculated CD band CD spectra Chem chromophore circular dichroism coefficient Cohn complex concentration conformation constant contribution Cotton effects creatine kinase cross-section denatured determined dialyzate diffusible components dilute electron density ellipticity enzyme equation equilibrium estimate exciton experimental factor Fasman function grams helical content helix hemocyanin hemoglobin intensity interaction kinase Kratky macromolecules magnetic measurements membrane method Moffitt molal molecular weight molecule myoglobin negative negative band nondiffusible observed obtained optical activity ORD curve osmometers osmotic pressure paramagnetic parameter partial specific volume particles peptide Phys Pilz plot polymer polypeptides positive procedure protein protein solution pulse radius of gyration random coil residues rotational strength rotatory sample Schellman Section shape solvent solvent medium spectrum sphere structure studies subunits T₁ temperature Tinoco tion transition wavelength X-ray zero