Physical Principles and Techniques of Protein Chemistry Part C, Part 3Sydney Leach Physical Principles and Techniques of Protein Chemistry, Part C focuses on the effects of intermolecular interactions that are transmitted between ligands and proteins and from protein to protein. This book discusses the density and volume change measurements; direct volume change; osmotic pressure; and small-angle X-ray scattering. The theory of particulate scattering; pulsed nuclear magnetic resonance; absorption of water by diamagnetic molecules; and use of least squares in data analysis are also elaborated. This text likewise covers the iteration process; optical rotatory dispersion and the main chain conformation of proteins; and basic relations for optically active molecules. Other topics include the circular dichroism, secondary structure of proteins, visible rotatory dispersion, and peptide cotton effects. This publication is intended for protein chemists, but is also useful to biologists, medical practitioners, and students researching on protein chemistry. |
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Page 2
... dialyzate density (grams per milliliter) oscillation time; inverse of resonance frequency apparent specific volume isopotential apparent specific volume milliliter fraction of protein solution having properties like dialyzate moles of ...
... dialyzate density (grams per milliliter) oscillation time; inverse of resonance frequency apparent specific volume isopotential apparent specific volume milliliter fraction of protein solution having properties like dialyzate moles of ...
Page 12
... dialyzate phase. Because these quantities v' and ¢' are still recognized generally by the presence of the primes, a change in the designations at this time would probably contribute to the confusion which has surrounded this subject ...
... dialyzate phase. Because these quantities v' and ¢' are still recognized generally by the presence of the primes, a change in the designations at this time would probably contribute to the confusion which has surrounded this subject ...
Page 13
... dialyzate (of unlimited volume), the derivatives (Zip/802)” are obtained rather than (Hp/802),“; the subscript ,u. denotes that each of the diffusible components has the same chemical potential in every phase. The values of (tip/502) ...
... dialyzate (of unlimited volume), the derivatives (Zip/802)” are obtained rather than (Hp/802),“; the subscript ,u. denotes that each of the diffusible components has the same chemical potential in every phase. The values of (tip/502) ...
Page 14
... dialyzate to a dialyzed protein solution. This procedure, in effect, yields values for v°' rather than {12° (Casassa ... dialyzate (Giintelberg and Linderstrcm-Lang, 1949; Casassa and Eisenberg, 1960, 1961). The composition of the ...
... dialyzate to a dialyzed protein solution. This procedure, in effect, yields values for v°' rather than {12° (Casassa ... dialyzate (Giintelberg and Linderstrcm-Lang, 1949; Casassa and Eisenberg, 1960, 1961). The composition of the ...
Page 15
... dialyzate composition, in which case is is negative; i.e., $3 is the amount of component 3 which must be removed from the solution when a gram of the protein is added. In this event, it may be more convenient to visualize 02' as the sum ...
... dialyzate composition, in which case is is negative; i.e., $3 is the amount of component 3 which must be removed from the solution when a gram of the protein is added. In this event, it may be more convenient to visualize 02' as the sum ...
Contents
1 | |
77 | |
Chapter 19 SmallAngle Xray Scattering | 141 |
Chapter 20 Pulsed Nuclear Magnetic Resonance | 245 |
Chapter 21 The Use of Least Squares in Data Analysis | 301 |
Chapter 22 Optical Rotatory Dispersion and the Main Chain Conformation of Proteins | 357 |
Chapter 23 Circular Dichroism | 445 |
Author Index | 595 |
Subject Index | 609 |
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Common terms and phrases
a-helix absorption acid Amer angle B-structure Beychok Biochem Biochemistry Biol Blout calculated CD band CD spectra Chem chromophore circular dichroism coefficient Cohn coil concentration conformation constant contribution Cotton effects creatine kinase cross-section defined definition denatured determined dialyzate diffusible components dipole disulfide electron density ellipticity enzyme equation equilibrium exciton experimental Fasman field find first fit function grams helix hemoglobin intensity interaction Kratky lysozyme magnetic measurements membrane method molal mole molecular weight molecule myoglobin negative negative band obtained optical activity ORD curve osmotic pressure parameters partial specific volume peptide Phys Pilz polymer polypeptides positive protein protein solution Pysh radius of gyration random coil residues ribonuclease rotational strength rotatory sample scattering curve Schellman Section shape significant small-angle solvent solvent medium spectrum studies subunits sufficiently temperature theoretical theory Tinoco tion transition tyrosine wavelength Woody X-ray zero