Physical Principles and Techniques of Protein Chemistry Part C, Part 3Sydney Leach Physical Principles and Techniques of Protein Chemistry, Part C focuses on the effects of intermolecular interactions that are transmitted between ligands and proteins and from protein to protein. This book discusses the density and volume change measurements; direct volume change; osmotic pressure; and small-angle X-ray scattering. The theory of particulate scattering; pulsed nuclear magnetic resonance; absorption of water by diamagnetic molecules; and use of least squares in data analysis are also elaborated. This text likewise covers the iteration process; optical rotatory dispersion and the main chain conformation of proteins; and basic relations for optically active molecules. Other topics include the circular dichroism, secondary structure of proteins, visible rotatory dispersion, and peptide cotton effects. This publication is intended for protein chemists, but is also useful to biologists, medical practitioners, and students researching on protein chemistry. |
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Page 2
... molal volume weight fraction of a component turnip yellow mosaic virus polarizability of a species net grams of component j (per gram protein) transported across a semipermeable membrane during dialysis chemical potential microliter ...
... molal volume weight fraction of a component turnip yellow mosaic virus polarizability of a species net grams of component j (per gram protein) transported across a semipermeable membrane during dialysis chemical potential microliter ...
Page 4
... molal) volumes remain constant as long as the composition does not vary, regardless of the total mass (and volume) of the system. The partial molal volume V is defined analogously by substituting the number of moles n for grams of mass ...
... molal) volumes remain constant as long as the composition does not vary, regardless of the total mass (and volume) of the system. The partial molal volume V is defined analogously by substituting the number of moles n for grams of mass ...
Page 5
... molal free energies or chemical potentials and are denoted usually as G or p.. The free energy G, like entropy S and enthalpy H, is a derived extensive property rather than a directly measured one such as volume, so that total values ...
... molal free energies or chemical potentials and are denoted usually as G or p.. The free energy G, like entropy S and enthalpy H, is a derived extensive property rather than a directly measured one such as volume, so that total values ...
Page 11
... molal volume is obtained.) The definition implies that the solvent medium behaves ideally with respect to its volume contribution. The solvent, of course, cannot be assigned a definite three-dimensional domain in the solution containing ...
... molal volume is obtained.) The definition implies that the solvent medium behaves ideally with respect to its volume contribution. The solvent, of course, cannot be assigned a definite three-dimensional domain in the solution containing ...
Page 55
Sydney Leach. molal protein solution without loss of generality.“] According to Eq. (45), 5,- (j = 1, 3) includes not only the gain or loss in mass of the subscripted diffusible component per gram of dry protein during equilibration ...
Sydney Leach. molal protein solution without loss of generality.“] According to Eq. (45), 5,- (j = 1, 3) includes not only the gain or loss in mass of the subscripted diffusible component per gram of dry protein during equilibration ...
Contents
1 | |
77 | |
Chapter 19 SmallAngle Xray Scattering | 141 |
Chapter 20 Pulsed Nuclear Magnetic Resonance | 245 |
Chapter 21 The Use of Least Squares in Data Analysis | 301 |
Chapter 22 Optical Rotatory Dispersion and the Main Chain Conformation of Proteins | 357 |
Chapter 23 Circular Dichroism | 445 |
Author Index | 595 |
Subject Index | 609 |
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Common terms and phrases
a-helix absorption acid Amer angle B-structure Beychok Biochem Biochemistry Biol Blout calculated CD band CD spectra Chem chromophore circular dichroism coefficient Cohn coil concentration conformation constant contribution Cotton effects creatine kinase cross-section defined definition denatured determined dialyzate diffusible components dipole disulfide electron density ellipticity enzyme equation equilibrium exciton experimental Fasman field find first fit function grams helix hemoglobin intensity interaction Kratky lysozyme magnetic measurements membrane method molal mole molecular weight molecule myoglobin negative negative band obtained optical activity ORD curve osmotic pressure parameters partial specific volume peptide Phys Pilz polymer polypeptides positive protein protein solution Pysh radius of gyration random coil residues ribonuclease rotational strength rotatory sample scattering curve Schellman Section shape significant small-angle solvent solvent medium spectrum studies subunits sufficiently temperature theoretical theory Tinoco tion transition tyrosine wavelength Woody X-ray zero