Physical Principles and Techniques of Protein Chemistry Part C, Part 3Sydney Leach Physical Principles and Techniques of Protein Chemistry, Part C focuses on the effects of intermolecular interactions that are transmitted between ligands and proteins and from protein to protein. This book discusses the density and volume change measurements; direct volume change; osmotic pressure; and small-angle X-ray scattering. The theory of particulate scattering; pulsed nuclear magnetic resonance; absorption of water by diamagnetic molecules; and use of least squares in data analysis are also elaborated. This text likewise covers the iteration process; optical rotatory dispersion and the main chain conformation of proteins; and basic relations for optically active molecules. Other topics include the circular dichroism, secondary structure of proteins, visible rotatory dispersion, and peptide cotton effects. This publication is intended for protein chemists, but is also useful to biologists, medical practitioners, and students researching on protein chemistry. |
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Page vi
... Molecules . References . . . 21. The Use of Least Squares in Data Analysis R. D. B. Fraser and E. Suzuki Glossary of Symbols . I. Introduction . II. Outline of Theory III. The Iteration Process IV. Statistical Aspects V. Model Functions ...
... Molecules . References . . . 21. The Use of Least Squares in Data Analysis R. D. B. Fraser and E. Suzuki Glossary of Symbols . I. Introduction . II. Outline of Theory III. The Iteration Process IV. Statistical Aspects V. Model Functions ...
Page 22
... molecules. If the polarizability and number of molecules of each component remain constant or can be evaluated accurately for a process, AV may be calculated (cf. Kauzmann, 1959). A recent application of this method, including ...
... molecules. If the polarizability and number of molecules of each component remain constant or can be evaluated accurately for a process, AV may be calculated (cf. Kauzmann, 1959). A recent application of this method, including ...
Page 71
... molecule (usually water) must exist at the surface of the macromolecule from steric considerations alone. It is especially important to note that different values of 51 or 5;, obtained with different solvent compositions cannot be ...
... molecule (usually water) must exist at the surface of the macromolecule from steric considerations alone. It is especially important to note that different values of 51 or 5;, obtained with different solvent compositions cannot be ...
Page 78
... molecule monomer species of a nondiffusible component (usually subscript) molecular weight of component or species i ... molecules in a mole pressure molar gas constant temperature (Kelvin scale) total volume partial molal volume of ...
... molecule monomer species of a nondiffusible component (usually subscript) molecular weight of component or species i ... molecules in a mole pressure molar gas constant temperature (Kelvin scale) total volume partial molal volume of ...
Page 79
... molecule or ion interactions and interactions between mixed macromolecular components, which sometimes are compounded by cross-association of their subunits. Hence, osmotic pressure can be a very useful method in combination with other ...
... molecule or ion interactions and interactions between mixed macromolecular components, which sometimes are compounded by cross-association of their subunits. Hence, osmotic pressure can be a very useful method in combination with other ...
Contents
1 | |
77 | |
Chapter 19 SmallAngle Xray Scattering | 141 |
Chapter 20 Pulsed Nuclear Magnetic Resonance | 245 |
Chapter 21 The Use of Least Squares in Data Analysis | 301 |
Chapter 22 Optical Rotatory Dispersion and the Main Chain Conformation of Proteins | 357 |
Chapter 23 Circular Dichroism | 445 |
Author Index | 595 |
Subject Index | 609 |
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Common terms and phrases
a-helix absorption acid Amer angle B-structure Beychok Biochem Biochemistry Biol Blout calculated CD band CD spectra Chem chromophore circular dichroism coefficient Cohn coil concentration conformation constant contribution Cotton effects creatine kinase cross-section defined definition denatured determined dialyzate diffusible components dipole disulfide electron density ellipticity enzyme equation equilibrium exciton experimental Fasman field find first fit function grams helix hemoglobin intensity interaction Kratky lysozyme magnetic measurements membrane method molal mole molecular weight molecule myoglobin negative negative band obtained optical activity ORD curve osmotic pressure parameters partial specific volume peptide Phys Pilz polymer polypeptides positive protein protein solution Pysh radius of gyration random coil residues ribonuclease rotational strength rotatory sample scattering curve Schellman Section shape significant small-angle solvent solvent medium spectrum studies subunits sufficiently temperature theoretical theory Tinoco tion transition tyrosine wavelength Woody X-ray zero