## Foundations of Colloid Science, Volume 2 |

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Page 685

Thus if Fav ( n ) is the

distance r ( averaged over all configurations of the rest of the molecules in the

system ) then the reversible work , W ( r ) needed to move the two molecules from

a ...

Thus if Fav ( n ) is the

**average**force between two molecules separated by adistance r ( averaged over all configurations of the rest of the molecules in the

system ) then the reversible work , W ( r ) needed to move the two molecules from

a ...

Page 692

Suppose we want to know the

intermolecular forces . If the N molecules are located at position { 11 , 12 , . . . , In }

the internal energy of this particular configuration is ( assuming pair interactions ,

u ( r ) ...

Suppose we want to know the

**average**internal energy of a liquid due tointermolecular forces . If the N molecules are located at position { 11 , 12 , . . . , In }

the internal energy of this particular configuration is ( assuming pair interactions ,

u ( r ) ...

Page 699

3 ) . However , experimental measurement of the intensity is really averaged over

many particle configurations . In other words , we require the

is given by : 1 = 1 = i # j ( 1 ) - W ? { 1 + ( Š X expliq . rs ) } } - 1 * Sarfar ' expliQ .

3 ) . However , experimental measurement of the intensity is really averaged over

many particle configurations . In other words , we require the

**average**( 15 ) whichis given by : 1 = 1 = i # j ( 1 ) - W ? { 1 + ( Š X expliq . rs ) } } - 1 * Sarfar ' expliQ .

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### Contents

INTRODUCTION TO STATISTICAL MECHANICS | 675 |

ADSORPTION FROM SOLUTION | 709 |

THE ELECTROKINETIC EFFECTS | 786 |

Copyright | |

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### Common terms and phrases

adsorbed adsorption applied approach approximation assumed average becomes behaviour bulk calculated Chapter charge Chem Colloid interface Sci colloidal component concentration constant correlation corresponding density depends described determined developed direction discussed dispersion distance double layer droplets effect electrical electrokinetic electrolyte emulsion energy equation equilibrium estimate et al example Exercise experimental expression factor field film flow fluid force fraction function given gives groups important increases interaction interface involved ions limit liquid material measured microemulsion molecules Note observed obtained occur pair particles phase positive possible potential present pressure problem procedure radius range reduces referred region result scattering Section separation shear rate shown solution specific spheres stability stress structure surface surface charge surface tension suspension temperature theory thin usually values viscosity volume zero